Isotope Effects in Deuterium Oxide Solution. I. Acid-Base Equilibria

Isotope Effects in Deuterium Oxide Solution. I. Acid-Base Equilibria

It is suggested that the deuterium oxide-solvent isotope effect on aqueous acid dissociation constants arises principally from changes in zero-point energy associated in turn principally with changes in hydrogen bonding strength and number of dissociation. These considerations led to a simple quanti...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of the American Chemical Society 1961-01, Vol.83 (1), p.42-47
Hauptverfasser: Bunton, C. A, Shiner, V. J
Format: Artikel
Sprache:eng
Schlagworte:
ACIDITY
ACIDS
BONDING
CHEMISTRY
DEUTERIUM COMPOUNDS
HYDROGEN
ISOTOPE EFFECTS
OXIDES
SOLUTIONS
SOLVENTS
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:It is suggested that the deuterium oxide-solvent isotope effect on aqueous acid dissociation constants arises principally from changes in zero-point energy associated in turn principally with changes in hydrogen bonding strength and number of dissociation. These considerations led to a simple quantitative method of estimating the isotope effect on acid-base equlibrium constants; this shows good agreement with experiment. (auth)
ISSN:0002-7863
1520-5126
DOI:10.1021/ja01462a008