Magnetic field and magnetic isotope effects on cage reactions in micellar solutions

Magnetic field and magnetic isotope effects on cage reactions in micellar solutions

Results of an investigation of the cage effects and /sup 13/C isotope enrichment in the photolysis of dibenzyl ketone and of labelled ketones in aqueous solutions containing hexadecyltrimethylammonium fluoride are reported. These results indicate that the nuclear spin isotope effects are significant...

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Veröffentlicht in:J. Am. Chem. Soc.; (United States) 1980-07, Vol.102 (14), p.4843-4845
Hauptverfasser: Turro, Nicholas J, Chow, Ming-Fea, Chung, Chao-Jen, Weed, Gregory C, Kraeutler, Bernhard
Format: Artikel
Sprache:eng
Schlagworte:
400500 > Photochemistry
CARBON 13
CARBON ISOTOPES
CHEMICAL REACTIONS
DATA
DECOMPOSITION
DEUTERIUM
EVEN-ODD NUCLEI
EXPERIMENTAL DATA
HYDROGEN ISOTOPES
INFORMATION
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
ISOTOPE EFFECTS
ISOTOPES
KETONES
LIGHT NUCLEI
MICELLAR SYSTEMS
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
STABLE ISOTOPES 400302 > Organic Chemistry-- Isotope Effects-- (-1987)
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Beschreibung
Zusammenfassung:Results of an investigation of the cage effects and /sup 13/C isotope enrichment in the photolysis of dibenzyl ketone and of labelled ketones in aqueous solutions containing hexadecyltrimethylammonium fluoride are reported. These results indicate that the nuclear spin isotope effects are significant in the photochemistry of dibenzyl ketone in micellar solutions. (BLM)
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00534a052