Anodic oxidation of uranocene. Evidence for new organouranium cations in solution

Voltammograms of uranocene in benzonitrile under an Ar atmosphere were recorded in studies to measure the controlled oxidation of the compound. The results indicated that cyclooctatetraene (COT) was librated during the electrolysis, and NMR data indicated that no more than /sup 1///sub 3/ of all the...

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Veröffentlicht in:	J. Am. Chem. Soc.; (United States) 1978-02, Vol.100 (3), p.1012-1013
Hauptverfasser:	Butcher, Jared A, Chambers, James Q, Pagni, Richard M
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ACTINIDE COMPLEXES CHEMICAL REACTIONS COMPLEXES INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ORGANIC COMPOUNDS ORGANOMETALLIC COMPOUNDS OXIDATION URANIUM COMPLEXES
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Beschreibung
Zusammenfassung:	Voltammograms of uranocene in benzonitrile under an Ar atmosphere were recorded in studies to measure the controlled oxidation of the compound. The results indicated that cyclooctatetraene (COT) was librated during the electrolysis, and NMR data indicated that no more than /sup 1///sub 3/ of all the COT ligand was librated as free COT. Combination of these data led to the conclusion that oxidation produced a dimeric or cluster product cation. (BLM)
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja00471a080