Phenylium (C6H5+) ion-molecule reactions studied by ion cyclotron resonance spectroscopy
Ion-assisted dehalogenation reactions of halobenzenes provide a convenient source of phenylium ions. Gas-phase reactions of phenylium ions with hydrogen, alkanes, alkyl halides, alkenes, and arenes have been studied by ion cyclotron resonance spectroscopy. Phenylium ions are strong electrophiles, at...
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| Veröffentlicht in: | J. Am. Chem. Soc.; (United States) 1977-08, Vol.99 (17), p.5583-5589 |
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| container_end_page | 5589 |
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| container_issue | 17 |
| container_start_page | 5583 |
| container_title | J. Am. Chem. Soc.; (United States) |
| container_volume | 99 |
| creator | Speranza, Maurizio Sefcik, Michael D Henis, Jay M. S Gaspar, Peter P |
| description | Ion-assisted dehalogenation reactions of halobenzenes provide a convenient source of phenylium ions. Gas-phase reactions of phenylium ions with hydrogen, alkanes, alkyl halides, alkenes, and arenes have been studied by ion cyclotron resonance spectroscopy. Phenylium ions are strong electrophiles, attacking sigma as well as ..pi.. and nonbonding electrons. The reactivity of phenylium ions has carbenoid characteristics. |
| doi_str_mv | 10.1021/ja00459a008 |
| format | Article |
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Soc</addtitle><date>1977-08-01</date><risdate>1977</risdate><volume>99</volume><issue>17</issue><spage>5583</spage><epage>5589</epage><pages>5583-5589</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>Ion-assisted dehalogenation reactions of halobenzenes provide a convenient source of phenylium ions. Gas-phase reactions of phenylium ions with hydrogen, alkanes, alkyl halides, alkenes, and arenes have been studied by ion cyclotron resonance spectroscopy. Phenylium ions are strong electrophiles, attacking sigma as well as ..pi.. and nonbonding electrons. The reactivity of phenylium ions has carbenoid characteristics.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/ja00459a008</doi><tpages>7</tpages></addata></record> |
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| identifier | ISSN: 0002-7863 |
| ispartof | J. Am. Chem. Soc.; (United States), 1977-08, Vol.99 (17), p.5583-5589 |
| issn | 0002-7863 1520-5126 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_ja00459a008 |
| source | ACS Publications |
| subjects | 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ALKANES ALKENES AROMATICS ARYL RADICALS CHEMICAL REACTIONS CRYOGENIC FLUIDS ELEMENTS FLUIDS HALOGENATED ALIPHATIC HYDROCARBONS HYDROCARBONS HYDROGEN INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ION CYCLOTRON RESONANCE SPECTROSCOPY ION SPECTROSCOPY NONMETALS ORGANIC COMPOUNDS ORGANIC HALOGEN COMPOUNDS PHENYL RADICALS RADICALS SPECTROSCOPY |
| title | Phenylium (C6H5+) ion-molecule reactions studied by ion cyclotron resonance spectroscopy |
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