Phenylium (C6H5+) ion-molecule reactions studied by ion cyclotron resonance spectroscopy

Ion-assisted dehalogenation reactions of halobenzenes provide a convenient source of phenylium ions. Gas-phase reactions of phenylium ions with hydrogen, alkanes, alkyl halides, alkenes, and arenes have been studied by ion cyclotron resonance spectroscopy. Phenylium ions are strong electrophiles, at...

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Veröffentlicht in:	J. Am. Chem. Soc.; (United States) 1977-08, Vol.99 (17), p.5583-5589
Hauptverfasser:	Speranza, Maurizio, Sefcik, Michael D, Henis, Jay M. S, Gaspar, Peter P
Format:	Artikel
Sprache:	eng
Schlagworte:	400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ALKANES ALKENES AROMATICS ARYL RADICALS CHEMICAL REACTIONS CRYOGENIC FLUIDS ELEMENTS FLUIDS HALOGENATED ALIPHATIC HYDROCARBONS HYDROCARBONS HYDROGEN INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ION CYCLOTRON RESONANCE SPECTROSCOPY ION SPECTROSCOPY NONMETALS ORGANIC COMPOUNDS ORGANIC HALOGEN COMPOUNDS PHENYL RADICALS RADICALS SPECTROSCOPY
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Beschreibung
Zusammenfassung:	Ion-assisted dehalogenation reactions of halobenzenes provide a convenient source of phenylium ions. Gas-phase reactions of phenylium ions with hydrogen, alkanes, alkyl halides, alkenes, and arenes have been studied by ion cyclotron resonance spectroscopy. Phenylium ions are strong electrophiles, attacking sigma as well as ..pi.. and nonbonding electrons. The reactivity of phenylium ions has carbenoid characteristics.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja00459a008