Deuterium isotope effects on the solvolysis of 1-(1-adamantyl)ethyl sulfonate esters

Deuterium isotope effects on the solvolysis of 1-(1-adamantyl)ethyl sulfonate esters

Results are reported of an extensive study of the solvolysis of the title esters which shows that steric hindrance is not the cause of the reported lower isotope effect. Data is given on solvolysis rates ..cap alpha..-d and ..beta..-d/sub 3/ rate effects and products for the title esters in nine dif...

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Veröffentlicht in:J. Am. Chem. Soc.; (United States) 1982-01, Vol.104 (1), p.354-355
Hauptverfasser: Shiner, V. J, Neumann, Thomas E, Fisher, Robert D
Format: Artikel
Sprache:eng
Schlagworte:
400302 - Organic Chemistry- Isotope Effects- (-1987)
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DATA
DECOMPOSITION
DEUTERIUM
ESTERS
EXPERIMENTAL DATA
HYDROGEN ISOTOPES
INFORMATION
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
ISOTOPE EFFECTS
ISOTOPES
KINETICS
LIGHT NUCLEI
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
REACTION KINETICS
SOLVOLYSIS
STABLE ISOTOPES
SULFONIC ACID ESTERS
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Beschreibung
Zusammenfassung:Results are reported of an extensive study of the solvolysis of the title esters which shows that steric hindrance is not the cause of the reported lower isotope effect. Data is given on solvolysis rates ..cap alpha..-d and ..beta..-d/sub 3/ rate effects and products for the title esters in nine different solvents.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00365a092