Photochemistry of aqueous permanganate ion

The photodecomposition of aqueous MnO/sub 4//sup -/ with a broadband source has been investigated. The products of the decomposition have been firmly identified. Trapping studies suggest the existence of a long-lived intermediate in the reaction; a structure for this intermediate and a basis for its...

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Veröffentlicht in:	J. Am. Chem. Soc.; (United States) 1987-05, Vol.109 (10), p.3003-3010
Hauptverfasser:	Lee, Donald G, Moylan, Christopher R, Hayashi, Takatoshi, Brauman, John I
Format:	Artikel
Sprache:	eng
Schlagworte:	ABSORPTION SPECTROSCOPY ANIONS AQUEOUS SOLUTIONS CHARGED PARTICLES CHEMICAL REACTION KINETICS CHEMICAL REACTIONS CHEMISTRY DATA DECOMPOSITION DISPERSIONS EFFICIENCY Exact sciences and technology EXPERIMENTAL DATA General and physical chemistry INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IONS KINETICS MANGANESE COMPOUNDS MIXTURES NUMERICAL DATA OXYGEN COMPOUNDS PERMANGANATES PHOTOCHEMICAL REACTIONS PHOTOCHEMISTRY PHOTOLYSIS Physical chemistry of induced reactions (with radiations, particles and ultrasonics) QUANTUM EFFICIENCY REACTION INTERMEDIATES REACTION KINETICS SOLUTIONS SPECTROSCOPY TRANSITION ELEMENT COMPOUNDS 400500 > Photochemistry
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Beschreibung
Zusammenfassung:	The photodecomposition of aqueous MnO/sub 4//sup -/ with a broadband source has been investigated. The products of the decomposition have been firmly identified. Trapping studies suggest the existence of a long-lived intermediate in the reaction; a structure for this intermediate and a basis for its long life are proposed.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja00244a023