The Bismuth–Bismuth Trichloride System

The Bismuth–Bismuth Trichloride System

A phase equilibrium study of the bismuth-bismuth trichloride system has been carried out. The experimental techniques included sampling at temperature, thermal analysis, and visual observations. The miscibility gap was found to be closed at a consolute tempenature of 780 and 51 mole % Bi. In the two...

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Veröffentlicht in:Journal of Physical Chemistry (U.S.) 1959-02, Vol.63 (2), p.230-233
Hauptverfasser: Yosim, S. J, Darnell, A J, Gehman, W. G, Mayer, S. W
Format: Artikel
Sprache:eng
Schlagworte:
BISMUTH
BISMUTH CHLORIDES
CHEMISTRY
EXPANSION
HIGH TEMPERATURE
LIQUIDS
MIXING
PHASE DIAGRAMS
SAMPLING
SOLIDS
SOLUBILITY
TEMPERATURE
THERMAL ANALYSIS
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Zusammenfassung:A phase equilibrium study of the bismuth-bismuth trichloride system has been carried out. The experimental techniques included sampling at temperature, thermal analysis, and visual observations. The miscibility gap was found to be closed at a consolute tempenature of 780 and 51 mole % Bi. In the two liquid phase region, the solubility of the salt in the metal increased with increasing temperature while the solubility of bismuth in bismuth trichloride decreased from 45% at 320 to 28% at about 550 . Results in the liquid-solid region are reported and compared with those of earlier workers. (auth)
ISSN:0022-3654
1541-5740
DOI:10.1021/j150572a023