An Unsymmetrical, Doubly Bridged Diiron(II) Complex with Readily Accessible Coordination Sites

An Unsymmetrical, Doubly Bridged Diiron(II) Complex with Readily Accessible Coordination Sites

The reactivity of the unsymmetrical diiron(II) complex ({mu}-alkoxo)({mu}-carboxylato)diiron(II) (1) toward the thiocyanate ion is directed to the iron center which has the lesser number of donor atoms contributed by the unsymmetrical bridging ligand rather than by availability of a vacant coordinat...

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Veröffentlicht in:Inorganic Chemistry 1996-03, Vol.35 (7), p.1749-1750
Hauptverfasser: Satcher, Joe H, Balch, Alan L, Olmstead, Marilyn M, Droege, Michael W
Format: Artikel
Sprache:eng
Schlagworte:
40 CHEMISTRY
CHEMICAL ACTIVATION
CHEMICAL REACTIONS
CRYSTAL STRUCTURE
IRON COMPLEXES
THIOCYANATES
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Zusammenfassung:The reactivity of the unsymmetrical diiron(II) complex ({mu}-alkoxo)({mu}-carboxylato)diiron(II) (1) toward the thiocyanate ion is directed to the iron center which has the lesser number of donor atoms contributed by the unsymmetrical bridging ligand rather than by availability of a vacant coordination site. Structural evidence for 1 and the product of reaction with SCN{sup -} is presented.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic951171l