Compound Formation by γ-Irradiation of Xenon-Fluorine Mixtures

Compound Formation by γ-Irradiation of Xenon-Fluorine Mixtures

Mixtures of Xe and F/sub 2/ in slightly greater than 2: 1 mole ratio of F/sub 2/ to Xe were exposed, in prefluorinated nickel containers, to high- intensity gamma radiation from Co/sup 60/ sources. The pressure was observed to fall, as it would if the two elements combined, and a solid product was l...

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Veröffentlicht in:Inorganic Chemistry (U.S.) 1963-10, Vol.2 (5), p.1064-1064
Hauptverfasser: MacKenzie, Donald R, Wiswall, Richard H
Format: Artikel
Sprache:eng
Schlagworte:
CHEMISTRY
COBALT 60
COMPOUNDS
EVAPORATION
FLUORINATION
FLUORINE
GAMMA RADIATION
GAMMA SOURCES
IRRADIATION
MIXING
NICKEL
NICKEL FLUORIDES
PREPARATION
PRESSURE
QUALITATIVE ANALYSIS
QUANTITY RATIO
RADIATION CHEMISTRY
SOLIDS
SUBLIMATION
VESSELS
XENON
XENON FLUORIDES
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Zusammenfassung:Mixtures of Xe and F/sub 2/ in slightly greater than 2: 1 mole ratio of F/sub 2/ to Xe were exposed, in prefluorinated nickel containers, to high- intensity gamma radiation from Co/sup 60/ sources. The pressure was observed to fall, as it would if the two elements combined, and a solid product was later obtained from the container, by sublimation. Results of analysis of the compound indicated a composition XeF/sub 3.0/, suggesting a mixture of difluoride and tetrafluoride. (P.C.H.)
ISSN:0020-1669
1520-510X
DOI:10.1021/ic50009a044