A Three-Dimensional Manganese(II) Complex Exhibiting Ferrimagnetic and Metamagnetic Behaviors

A Three-Dimensional Manganese(II) Complex Exhibiting Ferrimagnetic and Metamagnetic Behaviors

A three-dimensional complex, [Mn3(4-aba)6] n (1) (4-Haba = 4-aminobenzoic acid), consisting of manganese(II) chains and 4-aba bridging ligands, has been synthesized and characterized. Magnetic studies show that the compound behaves as a three-dimensional metamagnet built of homometallic ferrimagneti...

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Veröffentlicht in:Inorganic chemistry 2003-09, Vol.42 (18), p.5486-5488
Hauptverfasser: Wang, Ruihu, Gao, Enqing, Hong, Maochun, Gao, Song, Luo, Junhua, Lin, Zhenzhong, Han, Lei, Cao, Rong
Format: Artikel
Sprache:eng
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Zusammenfassung:A three-dimensional complex, [Mn3(4-aba)6] n (1) (4-Haba = 4-aminobenzoic acid), consisting of manganese(II) chains and 4-aba bridging ligands, has been synthesized and characterized. Magnetic studies show that the compound behaves as a three-dimensional metamagnet built of homometallic ferrimagnetic chains. The required noncompensation in spin moments is achieved by alternating interactions in an AF−AF−F sequence (AF = antiferromagnetic; F = ferromagnetic) by considering intrachain magnetic interactions.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic034550k