A K3-containing trigonal-bipyramidal cluster: synthesis of (KSCN)3.5HMPA by reaction of solid NH4SCN with solid K or KH in toluene/HMPA and its crystal structure revealing a triangle of three K+ ions linked by three equatorial .mu.2-HMPA ligands and bicapped by two .mu.3-HMPA ligands

A K3-containing trigonal-bipyramidal cluster: synthesis of (KSCN)3.5HMPA by reaction of solid NH4SCN with solid K or KH in toluene/HMPA and its crystal structure revealing a triangle of three K+ ions linked by three equatorial .mu.2-HMPA ligands and bicapped by two .mu.3-HMPA ligands

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Veröffentlicht in:Inorganic chemistry 1989-05, Vol.28 (10), p.1767-1768
Hauptverfasser: Barr, Donald, Doyle, Michael J, Drake, Simon R, Raithby, Paul R, Snaith, Ronald, Wright, Dominic S
Format: Artikel
Sprache:eng
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ISSN:0020-1669
1520-510X
DOI:10.1021/ic00309a001