Reactions of Copper(II) Halides (Chloride, Bromide) with the Sulfur-Rich Donor 1,3-Dithiacyclohexane-2-thione (ptc). Synthesis, Crystal Structures, and Characterization of Three Different Copper Compounds: Trinuclear r Mixed-Valence [CuI2CuII(ptc)4Cl4], Polynuclear [CuI2(ptc)Br2]n.cntdot.(n/2)THF, and Dinuclear [CuI2(ptc)4Br2]

Reactions of Copper(II) Halides (Chloride, Bromide) with the Sulfur-Rich Donor 1,3-Dithiacyclohexane-2-thione (ptc). Synthesis, Crystal Structures, and Characterization of Three Different Copper Compounds: Trinuclear r Mixed-Valence [CuI2CuII(ptc)4Cl4], Polynuclear [CuI2(ptc)Br2]n.cntdot.(n/2)THF, and Dinuclear [CuI2(ptc)4Br2]

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Veröffentlicht in:Inorganic chemistry 1994-06, Vol.33 (13), p.3005-3009
Hauptverfasser: Bellitto, Carlo, Bigoli, Francesco, Deplano, Paola, Mercuri, Maria Laura, Pellinghelli, Maria Angela, Staulo, Gigliola, Trogu, Emanuele F
Format: Artikel
Sprache:eng
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ISSN:0020-1669
1520-510X
DOI:10.1021/ic00091a047