Process studies with a promoted transition metal-zeolite catalyst
The conversion of synthesis gas to gasoline-range hydrocarbons was investigated with a cobalt-thoria-zeolite catalyst. The coprecipitated transition metal and promoter were intimately mixed with ZSM-5 zeolite and then extruded with an alumina binder. Tests were conducted in a gradientless reactor, w...
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| Veröffentlicht in: | Ind. Eng. Chem., Prod. Res. Dev.; (United States) Prod. Res. Dev.; (United States), 1984-09, Vol.23 (3), p.388-393 |
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| container_title | Ind. Eng. Chem., Prod. Res. Dev.; (United States) |
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| creator | Pennline, Henry W Gormley, Robert J Schehl, Richard R |
| description | The conversion of synthesis gas to gasoline-range hydrocarbons was investigated with a cobalt-thoria-zeolite catalyst. The coprecipitated transition metal and promoter were intimately mixed with ZSM-5 zeolite and then extruded with an alumina binder. Tests were conducted in a gradientless reactor, where initial results of high yields of gasoline-range hydrocarbons with a low ratio synthesis gas led to an extensive study of the catalyst. The effects of support, temperature (220-320C), pressure (1.14-2.17 MPa), and feed gas composition (1H2/1CO-3H2/1CO) on catalyst activity, stability, and product selectivity are discussed. Analyses of the deactivated bifunctional catalyst are also reported. |
| doi_str_mv | 10.1021/i300015a013 |
| format | Article |
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The coprecipitated transition metal and promoter were intimately mixed with ZSM-5 zeolite and then extruded with an alumina binder. Tests were conducted in a gradientless reactor, where initial results of high yields of gasoline-range hydrocarbons with a low ratio synthesis gas led to an extensive study of the catalyst. The effects of support, temperature (220-320C), pressure (1.14-2.17 MPa), and feed gas composition (1H2/1CO-3H2/1CO) on catalyst activity, stability, and product selectivity are discussed. Analyses of the deactivated bifunctional catalyst are also reported.</description><identifier>ISSN: 0196-4321</identifier><identifier>EISSN: 1541-4841</identifier><identifier>DOI: 10.1021/i300015a013</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>090121 - Hydrocarbon Fuels- Chemical Synthesis- (1976-1989) ; 10 SYNTHETIC FUELS ; ACTINIDE COMPOUNDS ; Applied sciences ; CATALYST SUPPORTS ; CATALYTIC EFFECTS ; CHALCOGENIDES ; CHEMICAL REACTIONS ; COBALT ; DATA ; ELEMENTS ; Energy ; Exact sciences and technology ; EXPERIMENTAL DATA ; FISCHER-TROPSCH SYNTHESIS ; FLUIDS ; Fuel processing. Carbochemistry and petrochemistry ; FUELS ; GASES ; INFORMATION ; INORGANIC ION EXCHANGERS ; ION EXCHANGE MATERIALS ; LIQUID FUELS ; MATERIALS ; METALS ; MINERALS ; NUMERICAL DATA ; OXIDES ; OXYGEN COMPOUNDS ; Solid fuel processing (coal, coke, brown coal, peat, wood, etc.) ; SYNTHESIS GAS ; TEMPERATURE EFFECTS ; THORIUM COMPOUNDS ; THORIUM OXIDES ; TRANSITION ELEMENTS ; ZEOLITES</subject><ispartof>Ind. Eng. Chem., Prod. Res. Dev.; (United States), 1984-09, Vol.23 (3), p.388-393</ispartof><rights>1985 INIST-CNRS</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a393t-7451f4d8a9f7f399ea2053d5dd7daffb4a6efb383d2ccce0f14a3316489c05153</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/i300015a013$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/i300015a013$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,885,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=8943891$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/6140604$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Pennline, Henry W</creatorcontrib><creatorcontrib>Gormley, Robert J</creatorcontrib><creatorcontrib>Schehl, Richard R</creatorcontrib><creatorcontrib>Dept. of Energy, Pittsburgh, PA</creatorcontrib><title>Process studies with a promoted transition metal-zeolite catalyst</title><title>Ind. Eng. Chem., Prod. Res. Dev.; (United States)</title><addtitle>Ind. Eng. Chem. Prod. Res. Dev</addtitle><description>The conversion of synthesis gas to gasoline-range hydrocarbons was investigated with a cobalt-thoria-zeolite catalyst. The coprecipitated transition metal and promoter were intimately mixed with ZSM-5 zeolite and then extruded with an alumina binder. Tests were conducted in a gradientless reactor, where initial results of high yields of gasoline-range hydrocarbons with a low ratio synthesis gas led to an extensive study of the catalyst. The effects of support, temperature (220-320C), pressure (1.14-2.17 MPa), and feed gas composition (1H2/1CO-3H2/1CO) on catalyst activity, stability, and product selectivity are discussed. Analyses of the deactivated bifunctional catalyst are also reported.</description><subject>090121 - Hydrocarbon Fuels- Chemical Synthesis- (1976-1989)</subject><subject>10 SYNTHETIC FUELS</subject><subject>ACTINIDE COMPOUNDS</subject><subject>Applied sciences</subject><subject>CATALYST SUPPORTS</subject><subject>CATALYTIC EFFECTS</subject><subject>CHALCOGENIDES</subject><subject>CHEMICAL REACTIONS</subject><subject>COBALT</subject><subject>DATA</subject><subject>ELEMENTS</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>FISCHER-TROPSCH SYNTHESIS</subject><subject>FLUIDS</subject><subject>Fuel processing. Carbochemistry and petrochemistry</subject><subject>FUELS</subject><subject>GASES</subject><subject>INFORMATION</subject><subject>INORGANIC ION EXCHANGERS</subject><subject>ION EXCHANGE MATERIALS</subject><subject>LIQUID FUELS</subject><subject>MATERIALS</subject><subject>METALS</subject><subject>MINERALS</subject><subject>NUMERICAL DATA</subject><subject>OXIDES</subject><subject>OXYGEN COMPOUNDS</subject><subject>Solid fuel processing (coal, coke, brown coal, peat, wood, etc.)</subject><subject>SYNTHESIS GAS</subject><subject>TEMPERATURE EFFECTS</subject><subject>THORIUM COMPOUNDS</subject><subject>THORIUM OXIDES</subject><subject>TRANSITION ELEMENTS</subject><subject>ZEOLITES</subject><issn>0196-4321</issn><issn>1541-4841</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1984</creationdate><recordtype>article</recordtype><recordid>eNpt0MlKBDEQBuAgCo7LyRdoRPAgralJ0stRxxUHHFAvXkKZTjA60xlSEZenN9IiHjyFkK_CXz9jO8APgY_hyAvOOSjkIFbYCJSEUjYSVtmIQ1uVUoxhnW0QPWdVVVCP2PEsBmOJCkqvnbdUvPn0VGCxjGERku2KFLEnn3zoi4VNOC8_bZj7ZAuD-fZBaYutOZyT3f45N9n9-dnd5LKc3lxcTY6nJYpWpLKWCpzsGmxd7UTbWhxzJTrVdXWHzj1KrKx7FI3oxsYYyx1IFAIq2bSGK1Bik-0O_wZKXpPJGcyTCX1vTdIVSF5xmdHBgEwMRNE6vYx-gfFDA9ffFek_FWW9N-glksG5y6saT78jTStF00Jm5cA8Jfv--4zxRVe1qJW-m93qazU5Eaei1g_Z7w8eDenn8Br73Mu_Ab4AHFOAzg</recordid><startdate>19840901</startdate><enddate>19840901</enddate><creator>Pennline, Henry W</creator><creator>Gormley, Robert J</creator><creator>Schehl, Richard R</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19840901</creationdate><title>Process studies with a promoted transition metal-zeolite catalyst</title><author>Pennline, Henry W ; Gormley, Robert J ; Schehl, Richard R</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a393t-7451f4d8a9f7f399ea2053d5dd7daffb4a6efb383d2ccce0f14a3316489c05153</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1984</creationdate><topic>090121 - Hydrocarbon Fuels- Chemical Synthesis- (1976-1989)</topic><topic>10 SYNTHETIC FUELS</topic><topic>ACTINIDE COMPOUNDS</topic><topic>Applied sciences</topic><topic>CATALYST SUPPORTS</topic><topic>CATALYTIC EFFECTS</topic><topic>CHALCOGENIDES</topic><topic>CHEMICAL REACTIONS</topic><topic>COBALT</topic><topic>DATA</topic><topic>ELEMENTS</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>FISCHER-TROPSCH SYNTHESIS</topic><topic>FLUIDS</topic><topic>Fuel processing. Carbochemistry and petrochemistry</topic><topic>FUELS</topic><topic>GASES</topic><topic>INFORMATION</topic><topic>INORGANIC ION EXCHANGERS</topic><topic>ION EXCHANGE MATERIALS</topic><topic>LIQUID FUELS</topic><topic>MATERIALS</topic><topic>METALS</topic><topic>MINERALS</topic><topic>NUMERICAL DATA</topic><topic>OXIDES</topic><topic>OXYGEN COMPOUNDS</topic><topic>Solid fuel processing (coal, coke, brown coal, peat, wood, etc.)</topic><topic>SYNTHESIS GAS</topic><topic>TEMPERATURE EFFECTS</topic><topic>THORIUM COMPOUNDS</topic><topic>THORIUM OXIDES</topic><topic>TRANSITION ELEMENTS</topic><topic>ZEOLITES</topic><toplevel>online_resources</toplevel><creatorcontrib>Pennline, Henry W</creatorcontrib><creatorcontrib>Gormley, Robert J</creatorcontrib><creatorcontrib>Schehl, Richard R</creatorcontrib><creatorcontrib>Dept. of Energy, Pittsburgh, PA</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Ind. Eng. Chem., Prod. Res. Dev.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pennline, Henry W</au><au>Gormley, Robert J</au><au>Schehl, Richard R</au><aucorp>Dept. of Energy, Pittsburgh, PA</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Process studies with a promoted transition metal-zeolite catalyst</atitle><jtitle>Ind. Eng. Chem., Prod. Res. Dev.; (United States)</jtitle><addtitle>Ind. Eng. Chem. Prod. Res. Dev</addtitle><date>1984-09-01</date><risdate>1984</risdate><volume>23</volume><issue>3</issue><spage>388</spage><epage>393</epage><pages>388-393</pages><issn>0196-4321</issn><eissn>1541-4841</eissn><abstract>The conversion of synthesis gas to gasoline-range hydrocarbons was investigated with a cobalt-thoria-zeolite catalyst. The coprecipitated transition metal and promoter were intimately mixed with ZSM-5 zeolite and then extruded with an alumina binder. Tests were conducted in a gradientless reactor, where initial results of high yields of gasoline-range hydrocarbons with a low ratio synthesis gas led to an extensive study of the catalyst. The effects of support, temperature (220-320C), pressure (1.14-2.17 MPa), and feed gas composition (1H2/1CO-3H2/1CO) on catalyst activity, stability, and product selectivity are discussed. Analyses of the deactivated bifunctional catalyst are also reported.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/i300015a013</doi><tpages>6</tpages></addata></record> |
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| identifier | ISSN: 0196-4321 |
| ispartof | Ind. Eng. Chem., Prod. Res. Dev.; (United States), 1984-09, Vol.23 (3), p.388-393 |
| issn | 0196-4321 1541-4841 |
| language | eng |
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| source | ACS Publications |
| subjects | 090121 - Hydrocarbon Fuels- Chemical Synthesis- (1976-1989) 10 SYNTHETIC FUELS ACTINIDE COMPOUNDS Applied sciences CATALYST SUPPORTS CATALYTIC EFFECTS CHALCOGENIDES CHEMICAL REACTIONS COBALT DATA ELEMENTS Energy Exact sciences and technology EXPERIMENTAL DATA FISCHER-TROPSCH SYNTHESIS FLUIDS Fuel processing. Carbochemistry and petrochemistry FUELS GASES INFORMATION INORGANIC ION EXCHANGERS ION EXCHANGE MATERIALS LIQUID FUELS MATERIALS METALS MINERALS NUMERICAL DATA OXIDES OXYGEN COMPOUNDS Solid fuel processing (coal, coke, brown coal, peat, wood, etc.) SYNTHESIS GAS TEMPERATURE EFFECTS THORIUM COMPOUNDS THORIUM OXIDES TRANSITION ELEMENTS ZEOLITES |
| title | Process studies with a promoted transition metal-zeolite catalyst |
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