Quality of Distillates from Repeated Recycle of Residue

The yields of gas, liquid, and coke from the coking of Athabasca vacuum residue were determined as a function of conversion of the residue. High conversion was achieved by subjecting the unconverted residue to repeated coking steps. The cumulative yield of liquid increased by 12% from stage 1 of cok...

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Veröffentlicht in:Energy & fuels 2002-03, Vol.16 (2), p.477-484
Hauptverfasser: Japanwala, Shakir, Chung, Keng H, Dettman, Heather D, Gray, Murray R
Format: Artikel
Sprache:eng
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Zusammenfassung:The yields of gas, liquid, and coke from the coking of Athabasca vacuum residue were determined as a function of conversion of the residue. High conversion was achieved by subjecting the unconverted residue to repeated coking steps. The cumulative yield of liquid increased by 12% from stage 1 of coking, where 80% residue conversion was obtained, to stage 3 where over 97% cumulative residue conversion was obtained. The quality of the distillates obtained at each stage deteriorated based on the concentrations of nitrogen and polyaromatic hydrocarbons. Although coking reactions resulted in a significant decrease in the number of paraffinic chains, the average chain length remained constant. A mass balance showed that the aromatic carbon increased in the first coking step, then remained constant.
ISSN:0887-0624
1520-5029
DOI:10.1021/ef010234j