Synthesis of Molybdenum-Molybdenum Quadruple Bonds: A Multistep Advanced Synthesis Laboratory Experiment

An advanced synthetic inorganic experiment is described in which students prepare Mo2(O2CCH3)4, a species containing a quadruple metal-metal bond. They then study the ligand substitution chemistry of the compound to form the unbridged systems [Mo2Cl8]4- and resources.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of chemical education 1999-03, Vol.76 (3), p.404
Hauptverfasser:	Pence, Laura E, Weisgerber, Amy M, Maounis, Florence A
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	An advanced synthetic inorganic experiment is described in which students prepare Mo2(O2CCH3)4, a species containing a quadruple metal-metal bond. They then study the ligand substitution chemistry of the compound to form the unbridged systems [Mo2Cl8]4- and resources.
ISSN:	0021-9584 1938-1328
DOI:	10.1021/ed076p404