Catalytic Isomerization of Allylic Alcohols in Water

The isomerization of allylic alcohols in water, catalytically mediated by water-soluble metal complexes, is an elegant synthetic procedure for obtaining carbonyl compounds in a completely atom-economical eco-benign process with useful applications in natural-product synthesis and bulk chemical proce...

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Veröffentlicht in:ACS catalysis 2012-06, Vol.2 (6), p.1079-1086
Hauptverfasser: Lorenzo-Luis, Pablo, Romerosa, Antonio, Serrano-Ruiz, Manuel
Format: Artikel
Sprache:eng
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Zusammenfassung:The isomerization of allylic alcohols in water, catalytically mediated by water-soluble metal complexes, is an elegant synthetic procedure for obtaining carbonyl compounds in a completely atom-economical eco-benign process with useful applications in natural-product synthesis and bulk chemical processes. This overview aims to provide a view of the goals attained in catalyzed allylic alcohol isomerization in water and its promising applications.
ISSN:2155-5435
2155-5435
DOI:10.1021/cs300092d