Soft chemical synthesis of new compounds with the hexagonal molybdenum oxide structure

In the current work, the authors have found that the alkali-metal brannerites undergo a novel leaching' reaction, which for A = Li leads to the formation of H{sub 0.13}V{sub 0.13}Mo{sub 0.87}O{sub 3}{center dot}nH{sub 2}O. Subsequent dehydration of this compound permits the preparation of a mic...

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Veröffentlicht in:	Chemistry of materials 1991-11, Vol.3 (6), p.1011-1012
Hauptverfasser:	Feist, Thomas P, Davies, Peter K
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties ALKALI METAL COMPOUNDS CHALCOGENIDES CHARGED PARTICLES CHEMICAL ANALYSIS CHEMICAL PREPARATION COHERENT SCATTERING CRYSTAL LATTICES CRYSTAL STRUCTURE DATA DIFFRACTION EXPERIMENTAL DATA GRAVIMETRIC ANALYSIS HEXAGONAL LATTICES HYDROGEN COMPOUNDS HYDROGEN IONS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IONS LATTICE PARAMETERS LITHIUM IONS MATERIALS MOLYBDENUM COMPOUNDS MOLYBDENUM OXIDES NUMERICAL DATA OXIDES OXYGEN COMPOUNDS POROUS MATERIALS QUANTITATIVE CHEMICAL ANALYSIS REFRACTORY METAL COMPOUNDS SCATTERING SODIUM COMPOUNDS SODIUM IONS SYNTHESIS THERMAL ANALYSIS THERMAL GRAVIMETRIC ANALYSIS TRANSITION ELEMENT COMPOUNDS VANADIUM COMPOUNDS VANADIUM OXIDES X-RAY DIFFRACTION
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Beschreibung
Zusammenfassung:	In the current work, the authors have found that the alkali-metal brannerites undergo a novel leaching' reaction, which for A = Li leads to the formation of H{sub 0.13}V{sub 0.13}Mo{sub 0.87}O{sub 3}{center dot}nH{sub 2}O. Subsequent dehydration of this compound permits the preparation of a microporous' form of hexagonal MoO{sub 3}, V{sub 0.13}Mo{sub 0.87}O{sub 2.935}, in which the one-dimensional tunnels are empty.
ISSN:	0897-4756 1520-5002
DOI:	10.1021/cm00018a012