Dimeric Rh(III) Complex Stabilized by Hydrogen Bonding: Building Block of a Nanoporous Supramolecular Assembly
The dimeric units [RhCl2(Hhmp)(hmp)]2, where Hhmp and hmp are 2-(hydroxymethyl)pyridine and anionic deprotonated ligand, respectively, is formed by strong hydrogen bonding interactions between pairs of Hhmp and hmp ligands that act as building blocks and self-assemble remarkably through aromatic π-π...
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| Veröffentlicht in: | Crystal growth & design 2009-04, Vol.9 (4), p.1643-1645 |
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| container_title | Crystal growth & design |
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| creator | Sarmah, Bhaskar Jyoti Dutta, Dipak Kumar |
| description | The dimeric units [RhCl2(Hhmp)(hmp)]2, where Hhmp and hmp are 2-(hydroxymethyl)pyridine and anionic deprotonated ligand, respectively, is formed by strong hydrogen bonding interactions between pairs of Hhmp and hmp ligands that act as building blocks and self-assemble remarkably through aromatic π-π and CH/-π interactions to generate a nanoporous supramolecular structure exhibiting permanent porosity and selective adsorption properties. |
| doi_str_mv | 10.1021/cg800987f |
| format | Article |
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| ispartof | Crystal growth & design, 2009-04, Vol.9 (4), p.1643-1645 |
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| source | American Chemical Society Journals |
| subjects | Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Organic compounds Physics Solid surfaces and solid-solid interfaces Structure of solids and liquids crystallography Structure of specific crystalline solids Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties) |
| title | Dimeric Rh(III) Complex Stabilized by Hydrogen Bonding: Building Block of a Nanoporous Supramolecular Assembly |
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