Dimeric Rh(III) Complex Stabilized by Hydrogen Bonding: Building Block of a Nanoporous Supramolecular Assembly

The dimeric units [RhCl2(Hhmp)(hmp)]2, where Hhmp and hmp are 2-(hydroxymethyl)pyridine and anionic deprotonated ligand, respectively, is formed by strong hydrogen bonding interactions between pairs of Hhmp and hmp ligands that act as building blocks and self-assemble remarkably through aromatic π-π...

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Veröffentlicht in:	Crystal growth & design 2009-04, Vol.9 (4), p.1643-1645
Hauptverfasser:	Sarmah, Bhaskar Jyoti, Dutta, Dipak Kumar
Format:	Artikel
Sprache:	eng
Schlagworte:	Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Organic compounds Physics Solid surfaces and solid-solid interfaces Structure of solids and liquids crystallography Structure of specific crystalline solids Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties)
Online-Zugang:	Volltext
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Zusammenfassung:	The dimeric units [RhCl2(Hhmp)(hmp)]2, where Hhmp and hmp are 2-(hydroxymethyl)pyridine and anionic deprotonated ligand, respectively, is formed by strong hydrogen bonding interactions between pairs of Hhmp and hmp ligands that act as building blocks and self-assemble remarkably through aromatic π-π and CH/-π interactions to generate a nanoporous supramolecular structure exhibiting permanent porosity and selective adsorption properties.
ISSN:	1528-7483 1528-7505
DOI:	10.1021/cg800987f