Three Supramolecular Isomers of Square Grid Networks from the Assembly of a Flexible Spacer and Co(NCS)2:  Structures and Polymer Transformation

Assemblies of 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene (bbtz) and Co(NCS)2 afford three supramolecular isomers [Co(bbtz)2(NCS)2] n of square grid networks depending on the assembly conditions. Polymer transformation phenomena are observed among them. Conformation analysis of the ligand is presented...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Crystal growth & design 2006-04, Vol.6 (4), p.994-998
Hauptverfasser: Peng, Yan-Fen, Ge, Hai-Yan, Li, Bao-Zong, Li, Bao-Long, Zhang, Yong
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Assemblies of 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene (bbtz) and Co(NCS)2 afford three supramolecular isomers [Co(bbtz)2(NCS)2] n of square grid networks depending on the assembly conditions. Polymer transformation phenomena are observed among them. Conformation analysis of the ligand is presented to understand the flexibility of the bbtz ligand that influences the assembly topological architectures.
ISSN:1528-7483
1528-7505
DOI:10.1021/cg050595f