Three Supramolecular Isomers of Square Grid Networks from the Assembly of a Flexible Spacer and Co(NCS)2: Structures and Polymer Transformation
Assemblies of 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene (bbtz) and Co(NCS)2 afford three supramolecular isomers [Co(bbtz)2(NCS)2] n of square grid networks depending on the assembly conditions. Polymer transformation phenomena are observed among them. Conformation analysis of the ligand is presented...
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Veröffentlicht in: | Crystal growth & design 2006-04, Vol.6 (4), p.994-998 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Assemblies of 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene (bbtz) and Co(NCS)2 afford three supramolecular isomers [Co(bbtz)2(NCS)2] n of square grid networks depending on the assembly conditions. Polymer transformation phenomena are observed among them. Conformation analysis of the ligand is presented to understand the flexibility of the bbtz ligand that influences the assembly topological architectures. |
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ISSN: | 1528-7483 1528-7505 |
DOI: | 10.1021/cg050595f |