Rational Synthesis and Characterization of Robust Microporous Metal−Organic Frameworks with Base Functionality

Employing pyrimidine-containing ligands such as 1-(4-pyridyl)-2-(4-pyrimydyl)ethene (L ) and 1-(4-pyridyl)-2-(3-methyl-4-pyridyl)ethene (L 3 ) in assembly with Co(SCN)2 affords robust porous coordination polymers with uncoordinated nitrogen atoms on the channel walls.

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Bibliographische Detailangaben
Veröffentlicht in:	Crystal growth & design 2006-05, Vol.6 (5), p.1059-1061
Hauptverfasser:	Shin, Dong Mok, Lee, In Su, Chung, Young Keun
Format:	Artikel
Sprache:	eng
Schlagworte:	Condensed matter: structure, mechanical and thermal properties Crystalline state (including molecular motions in solids) Crystallographic aspects of phase transformations pressure effects Exact sciences and technology Physics Structure of solids and liquids crystallography
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Beschreibung
Zusammenfassung:	Employing pyrimidine-containing ligands such as 1-(4-pyridyl)-2-(4-pyrimydyl)ethene (L ) and 1-(4-pyridyl)-2-(3-methyl-4-pyridyl)ethene (L 3 ) in assembly with Co(SCN)2 affords robust porous coordination polymers with uncoordinated nitrogen atoms on the channel walls.
ISSN:	1528-7483 1528-7505
DOI:	10.1021/cg0504399