Formation of Coordination Porphyrin Pentamers in New Supramolecular Complex of Fullerene:  {(ZnTPP)4·4-TPyP}·(C60)2·(C6H5CN)3.5

A new supramolecular complex of fullerene C60, {(ZnTPP)4·(4-TPyP)}·(C60)2·(C6H5CN)3.5 (ZnTPP:  zinc(II) tetraphenylporphyrin; 4-TPyP:  tetra(4-pyridyl)porphyrin) involving unusual pentamers containing five porphyrin fragments, was obtained. The crystal structure, IR and UV−vis−NIR spectra of the com...

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Veröffentlicht in:Crystal growth & design 2004-07, Vol.4 (4), p.643-646
Hauptverfasser: Konarev, Dmitri V, Litvinov, Alexey L, Neretin, Ivan S, Drichko, Natalia V, Slovokhotov, Yury L, Lyubovskaya, Rimma N, Howard, Judith A. K, Yufit, D. S
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Sprache:eng
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Zusammenfassung:A new supramolecular complex of fullerene C60, {(ZnTPP)4·(4-TPyP)}·(C60)2·(C6H5CN)3.5 (ZnTPP:  zinc(II) tetraphenylporphyrin; 4-TPyP:  tetra(4-pyridyl)porphyrin) involving unusual pentamers containing five porphyrin fragments, was obtained. The crystal structure, IR and UV−vis−NIR spectra of the complex, and the molecular structure of the pentamer are presented.
ISSN:1528-7483
1528-7505
DOI:10.1021/cg034259f