Formation of Coordination Porphyrin Pentamers in New Supramolecular Complex of Fullerene: {(ZnTPP)4·4-TPyP}·(C60)2·(C6H5CN)3.5
A new supramolecular complex of fullerene C60, {(ZnTPP)4·(4-TPyP)}·(C60)2·(C6H5CN)3.5 (ZnTPP: zinc(II) tetraphenylporphyrin; 4-TPyP: tetra(4-pyridyl)porphyrin) involving unusual pentamers containing five porphyrin fragments, was obtained. The crystal structure, IR and UV−vis−NIR spectra of the com...
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Veröffentlicht in: | Crystal growth & design 2004-07, Vol.4 (4), p.643-646 |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | A new supramolecular complex of fullerene C60, {(ZnTPP)4·(4-TPyP)}·(C60)2·(C6H5CN)3.5 (ZnTPP: zinc(II) tetraphenylporphyrin; 4-TPyP: tetra(4-pyridyl)porphyrin) involving unusual pentamers containing five porphyrin fragments, was obtained. The crystal structure, IR and UV−vis−NIR spectra of the complex, and the molecular structure of the pentamer are presented. |
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ISSN: | 1528-7483 1528-7505 |
DOI: | 10.1021/cg034259f |