1-D Coordination Polymers Made of Asymmetrical Copper Nitroxide Bis-Chelates
Mixed-ligand copper nitroxide complexes Cu(ptfa)L (ptfa = pivaloyltrifluoroacetonato, L = nitrile-substituted nitroxide enaminoketone) have been synthesized and characterized structurally and magnetically. The complexes are 1-D nitrile-bound coordination polymers in contrast to 2-D and 3-D Cu(hfac)L...
Gespeichert in:
| Veröffentlicht in: | Crystal growth & design 2004-05, Vol.4 (3), p.595-598 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 598 |
|---|---|
| container_issue | 3 |
| container_start_page | 595 |
| container_title | Crystal growth & design |
| container_volume | 4 |
| creator | Burdukov, Alexei B Gladkikh, Ella A Nefedova, Ekaterina V Tronin, Andrei V Roshchupkina, Galina I Pervukhina, Natalie V Shvedenkov, Yuri G Reznikov, Vladimir A |
| description | Mixed-ligand copper nitroxide complexes Cu(ptfa)L (ptfa = pivaloyltrifluoroacetonato, L = nitrile-substituted nitroxide enaminoketone) have been synthesized and characterized structurally and magnetically. The complexes are 1-D nitrile-bound coordination polymers in contrast to 2-D and 3-D Cu(hfac)L (hfac = hexafluoroacetylacetonato) studied earlier. The magnetic dimensionality of Cu(ptfa)L is zero, and weak ferromagnetic exchange of an intramolecular nature is observed. |
| doi_str_mv | 10.1021/cg034168i |
| format | Article |
| fullrecord | <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_cg034168i</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c848218943</sourcerecordid><originalsourceid>FETCH-LOGICAL-a257t-31427e72fc32acb06e82428392e1e85ad44388d504e3d4cbb61adbb093df7e943</originalsourceid><addsrcrecordid>eNpt0DtPwzAUBWALgUQpDPwDLwwMBj8TdyyhPKTwGGCOHPsGXCVxZAeJ_HuCCkxM5wyfrq4OQqeMXjDK2aV9o0KyTPs9tGCKa5IrqvZ_u9TiEB2ltKWU5pkQC1Qyco2LEKLzvRl96PFzaKcOYsIPxgEODV6nqetgjN6adqbDABE_-jGGTz-DK59I8Q6tGSEdo4PGtAlOfnKJXm82L8UdKZ9u74t1SQxX-UgEkzyHnDdWcGNrmoHmkmux4sBAK-OkFFo7RSUIJ21dZ8y4uqYr4ZocVlIs0fnuro0hpQhNNUTfmThVjFbfM1R_M8z2bGeNTdU2fMR-_uwf9wWkXltG</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>1-D Coordination Polymers Made of Asymmetrical Copper Nitroxide Bis-Chelates</title><source>ACS Publications</source><creator>Burdukov, Alexei B ; Gladkikh, Ella A ; Nefedova, Ekaterina V ; Tronin, Andrei V ; Roshchupkina, Galina I ; Pervukhina, Natalie V ; Shvedenkov, Yuri G ; Reznikov, Vladimir A</creator><creatorcontrib>Burdukov, Alexei B ; Gladkikh, Ella A ; Nefedova, Ekaterina V ; Tronin, Andrei V ; Roshchupkina, Galina I ; Pervukhina, Natalie V ; Shvedenkov, Yuri G ; Reznikov, Vladimir A</creatorcontrib><description>Mixed-ligand copper nitroxide complexes Cu(ptfa)L (ptfa = pivaloyltrifluoroacetonato, L = nitrile-substituted nitroxide enaminoketone) have been synthesized and characterized structurally and magnetically. The complexes are 1-D nitrile-bound coordination polymers in contrast to 2-D and 3-D Cu(hfac)L (hfac = hexafluoroacetylacetonato) studied earlier. The magnetic dimensionality of Cu(ptfa)L is zero, and weak ferromagnetic exchange of an intramolecular nature is observed.</description><identifier>ISSN: 1528-7483</identifier><identifier>EISSN: 1528-7505</identifier><identifier>DOI: 10.1021/cg034168i</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Crystal growth & design, 2004-05, Vol.4 (3), p.595-598</ispartof><rights>Copyright © 2004 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a257t-31427e72fc32acb06e82428392e1e85ad44388d504e3d4cbb61adbb093df7e943</citedby><cites>FETCH-LOGICAL-a257t-31427e72fc32acb06e82428392e1e85ad44388d504e3d4cbb61adbb093df7e943</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cg034168i$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cg034168i$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids></links><search><creatorcontrib>Burdukov, Alexei B</creatorcontrib><creatorcontrib>Gladkikh, Ella A</creatorcontrib><creatorcontrib>Nefedova, Ekaterina V</creatorcontrib><creatorcontrib>Tronin, Andrei V</creatorcontrib><creatorcontrib>Roshchupkina, Galina I</creatorcontrib><creatorcontrib>Pervukhina, Natalie V</creatorcontrib><creatorcontrib>Shvedenkov, Yuri G</creatorcontrib><creatorcontrib>Reznikov, Vladimir A</creatorcontrib><title>1-D Coordination Polymers Made of Asymmetrical Copper Nitroxide Bis-Chelates</title><title>Crystal growth & design</title><addtitle>Cryst. Growth Des</addtitle><description>Mixed-ligand copper nitroxide complexes Cu(ptfa)L (ptfa = pivaloyltrifluoroacetonato, L = nitrile-substituted nitroxide enaminoketone) have been synthesized and characterized structurally and magnetically. The complexes are 1-D nitrile-bound coordination polymers in contrast to 2-D and 3-D Cu(hfac)L (hfac = hexafluoroacetylacetonato) studied earlier. The magnetic dimensionality of Cu(ptfa)L is zero, and weak ferromagnetic exchange of an intramolecular nature is observed.</description><issn>1528-7483</issn><issn>1528-7505</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNpt0DtPwzAUBWALgUQpDPwDLwwMBj8TdyyhPKTwGGCOHPsGXCVxZAeJ_HuCCkxM5wyfrq4OQqeMXjDK2aV9o0KyTPs9tGCKa5IrqvZ_u9TiEB2ltKWU5pkQC1Qyco2LEKLzvRl96PFzaKcOYsIPxgEODV6nqetgjN6adqbDABE_-jGGTz-DK59I8Q6tGSEdo4PGtAlOfnKJXm82L8UdKZ9u74t1SQxX-UgEkzyHnDdWcGNrmoHmkmux4sBAK-OkFFo7RSUIJ21dZ8y4uqYr4ZocVlIs0fnuro0hpQhNNUTfmThVjFbfM1R_M8z2bGeNTdU2fMR-_uwf9wWkXltG</recordid><startdate>20040501</startdate><enddate>20040501</enddate><creator>Burdukov, Alexei B</creator><creator>Gladkikh, Ella A</creator><creator>Nefedova, Ekaterina V</creator><creator>Tronin, Andrei V</creator><creator>Roshchupkina, Galina I</creator><creator>Pervukhina, Natalie V</creator><creator>Shvedenkov, Yuri G</creator><creator>Reznikov, Vladimir A</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20040501</creationdate><title>1-D Coordination Polymers Made of Asymmetrical Copper Nitroxide Bis-Chelates</title><author>Burdukov, Alexei B ; Gladkikh, Ella A ; Nefedova, Ekaterina V ; Tronin, Andrei V ; Roshchupkina, Galina I ; Pervukhina, Natalie V ; Shvedenkov, Yuri G ; Reznikov, Vladimir A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a257t-31427e72fc32acb06e82428392e1e85ad44388d504e3d4cbb61adbb093df7e943</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Burdukov, Alexei B</creatorcontrib><creatorcontrib>Gladkikh, Ella A</creatorcontrib><creatorcontrib>Nefedova, Ekaterina V</creatorcontrib><creatorcontrib>Tronin, Andrei V</creatorcontrib><creatorcontrib>Roshchupkina, Galina I</creatorcontrib><creatorcontrib>Pervukhina, Natalie V</creatorcontrib><creatorcontrib>Shvedenkov, Yuri G</creatorcontrib><creatorcontrib>Reznikov, Vladimir A</creatorcontrib><collection>CrossRef</collection><jtitle>Crystal growth & design</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Burdukov, Alexei B</au><au>Gladkikh, Ella A</au><au>Nefedova, Ekaterina V</au><au>Tronin, Andrei V</au><au>Roshchupkina, Galina I</au><au>Pervukhina, Natalie V</au><au>Shvedenkov, Yuri G</au><au>Reznikov, Vladimir A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>1-D Coordination Polymers Made of Asymmetrical Copper Nitroxide Bis-Chelates</atitle><jtitle>Crystal growth & design</jtitle><addtitle>Cryst. Growth Des</addtitle><date>2004-05-01</date><risdate>2004</risdate><volume>4</volume><issue>3</issue><spage>595</spage><epage>598</epage><pages>595-598</pages><issn>1528-7483</issn><eissn>1528-7505</eissn><abstract>Mixed-ligand copper nitroxide complexes Cu(ptfa)L (ptfa = pivaloyltrifluoroacetonato, L = nitrile-substituted nitroxide enaminoketone) have been synthesized and characterized structurally and magnetically. The complexes are 1-D nitrile-bound coordination polymers in contrast to 2-D and 3-D Cu(hfac)L (hfac = hexafluoroacetylacetonato) studied earlier. The magnetic dimensionality of Cu(ptfa)L is zero, and weak ferromagnetic exchange of an intramolecular nature is observed.</abstract><pub>American Chemical Society</pub><doi>10.1021/cg034168i</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1528-7483 |
| ispartof | Crystal growth & design, 2004-05, Vol.4 (3), p.595-598 |
| issn | 1528-7483 1528-7505 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_cg034168i |
| source | ACS Publications |
| title | 1-D Coordination Polymers Made of Asymmetrical Copper Nitroxide Bis-Chelates |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-05T14%3A24%3A20IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=1-D%20Coordination%20Polymers%20Made%20of%20Asymmetrical%20Copper%20Nitroxide%20Bis-Chelates&rft.jtitle=Crystal%20growth%20&%20design&rft.au=Burdukov,%20Alexei%20B&rft.date=2004-05-01&rft.volume=4&rft.issue=3&rft.spage=595&rft.epage=598&rft.pages=595-598&rft.issn=1528-7483&rft.eissn=1528-7505&rft_id=info:doi/10.1021/cg034168i&rft_dat=%3Cacs_cross%3Ec848218943%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |