Halogen Bonding and Hydrogen Bonding Coexist in Driving Self-Assembly Process

A new class supramolecular architecture of 1,1,3,3-tetra-oxo-2-bromo-4,4,5,5,6,6-hexafluoro-1,3-dithiacyclohexane 1 and 2-methylpyrazine has been assembled through both hydrogen bonding and halogen bonding. However, stronger or weaker bases or electron donors such as pyrazine and N,N,N ‘ ,N ‘-tetram...

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Veröffentlicht in:Crystal growth & design 2004-01, Vol.4 (1), p.53-56
Hauptverfasser: Zhu, Shizheng, Xing, Chunhui, Xu, Wei, Jin, Guifang, Li, Zhanting
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container_title Crystal growth & design
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creator Zhu, Shizheng
Xing, Chunhui
Xu, Wei
Jin, Guifang
Li, Zhanting
description A new class supramolecular architecture of 1,1,3,3-tetra-oxo-2-bromo-4,4,5,5,6,6-hexafluoro-1,3-dithiacyclohexane 1 and 2-methylpyrazine has been assembled through both hydrogen bonding and halogen bonding. However, stronger or weaker bases or electron donors such as pyrazine and N,N,N ‘ ,N ‘-tetramethylenediamine (TMEDA) failed to give the corresponding supramolecule.
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subjects Aliphatic, non-condensed and condensed benzenic, and alicyclic compounds
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Organic compounds
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
title Halogen Bonding and Hydrogen Bonding Coexist in Driving Self-Assembly Process
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