Sonogashira Couplings Catalyzed by Fe Nanoparticles Containing ppm Levels of Reusable Pd, under Mild Aqueous Micellar Conditions
Nanoparticles derived from FeCl3 containing the ligand XPhos and only 500 ppm Pd effect Sonogashira couplings in water between rt and 45 °C. The entire aqueous reaction medium can be easily recycled using an “in-flask” extraction. Several tandem processes in one pot are illustrated, including a sequ...
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Veröffentlicht in: | ACS catalysis 2019-03, Vol.9 (3), p.2423-2431 |
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creator | Handa, Sachin Jin, Bo Bora, Pranjal P Wang, Ye Zhang, Xiaohua Gallou, Fabrice Reilly, John Lipshutz, Bruce H |
description | Nanoparticles derived from FeCl3 containing the ligand XPhos and only 500 ppm Pd effect Sonogashira couplings in water between rt and 45 °C. The entire aqueous reaction medium can be easily recycled using an “in-flask” extraction. Several tandem processes in one pot are illustrated, including a sequence involving five steps (10 reactions) in good overall yield. |
doi_str_mv | 10.1021/acscatal.9b00007 |
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title | Sonogashira Couplings Catalyzed by Fe Nanoparticles Containing ppm Levels of Reusable Pd, under Mild Aqueous Micellar Conditions |
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