Sonogashira Couplings Catalyzed by Fe Nanoparticles Containing ppm Levels of Reusable Pd, under Mild Aqueous Micellar Conditions

Nanoparticles derived from FeCl3 containing the ligand XPhos and only 500 ppm Pd effect Sonogashira couplings in water between rt and 45 °C. The entire aqueous reaction medium can be easily recycled using an “in-flask” extraction. Several tandem processes in one pot are illustrated, including a sequ...

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Veröffentlicht in:ACS catalysis 2019-03, Vol.9 (3), p.2423-2431
Hauptverfasser: Handa, Sachin, Jin, Bo, Bora, Pranjal P, Wang, Ye, Zhang, Xiaohua, Gallou, Fabrice, Reilly, John, Lipshutz, Bruce H
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container_end_page 2431
container_issue 3
container_start_page 2423
container_title ACS catalysis
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creator Handa, Sachin
Jin, Bo
Bora, Pranjal P
Wang, Ye
Zhang, Xiaohua
Gallou, Fabrice
Reilly, John
Lipshutz, Bruce H
description Nanoparticles derived from FeCl3 containing the ligand XPhos and only 500 ppm Pd effect Sonogashira couplings in water between rt and 45 °C. The entire aqueous reaction medium can be easily recycled using an “in-flask” extraction. Several tandem processes in one pot are illustrated, including a sequence involving five steps (10 reactions) in good overall yield.
doi_str_mv 10.1021/acscatal.9b00007
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title Sonogashira Couplings Catalyzed by Fe Nanoparticles Containing ppm Levels of Reusable Pd, under Mild Aqueous Micellar Conditions
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