High-Performance Ternary Organic Solar Cells Enabled by Introducing a New A‑DA′D‑A Guest Acceptor with Higher-Lying LUMO Level

A ternary strategy is viable to minimize the trade-off between short-circuit current density (J sc) and open-circuit voltage (V oc) in organic solar cells. Generally, the ternary OSCs can achieve a higher PCE than the binary counterparts by subtly utilizing the particular photoelectric properties of the third material. In this regard, we choose BTP-CC with a higher-lying LUMO level based on a fused TPBT (dithienothiophen­[3.2-b]-pyrrolobenzothiadiazole) central framework and CC (2-(6-oxo-5,6-dihydro-4H-cyclopenta [b]­thiophen-4-ylidene) malononitrile) flanking groups as the third component to broaden the light-absorption spectrum, regulate the bulk heterojunction (BHJ) morphology, improve the V oc, and reduce the charge recombination in OSCs. In addition, BTP-CC demonstrates intense intermolecular energy transfer to Y6 by fluorescence resonance energy transfer (FRET) pathway, which is due to the photoluminescence (PL) spectrum of BTP-CC covering the absorption region of Y6. The PM6:Y6:BTP-CC based ternary OSC achieves a champion PCE of 17.55%. Further investigation indicates that introduction of BTP-CC could reduce the trap states in OSCs, leading to an increased charge carrier density. Moreover, the incorporation of BTP-CC could improve the device stability. These results demonstrated that BTP-CC is important in improving the photovoltaic performance of ternary OSCs, and this work also provides a guideline for constructing ideal ternary OSCs in the future.