Selective Reductive Removal of Silver Ions from Acidic Solutions by Redox-Active Covalent Organic Frameworks

The selective removal and recovery of silver ions from an aqueous solution is necessary, owing to the toxicity, persistency, and recoverable value. Herein, we first reported that silver ions could be selectively removed from an acidic solution by utilizing redox-active covalent organic framework (COF) materials as an adsorbent, resulting in the loading of Ag nanoparticles (NPs) with a narrow size distribution onto the framework simultaneously. The redox-active COF not only showed promising performance in adsorbing silver ions but also had a high selectivity at a low pH value. Subsequently, it was found that the N sites of amine groups within the framework took responsibility for the Ag NP generation after the systematic investigation on the redox adsorption mechanism. Furthermore, the recycled Ag@COF materials could be further used as new adsorbents to remove Hg­(II) ions from water via NPs as a “bridge”, exhibiting ultrahigh atomic utilization (>100%). Accordingly, this work not only provides a novel insight for the use of redox-active COF in the removal of metal ions but also opens a new field for designing of functionalized COF for their potential application in diverse areas.