Coupling of a Copper Dye with a Copper Electrolyte: A Fascinating Springboard for Sustainable Dye-Sensitized Solar Cells

A simple new heteroleptic copper dye, bearing one 2,9-dimesityl-1,10-phenanthroline and a 6,6′-dimethyl-2,2′-bipyridine-4,4′-dibenzoic acid anchoring ligand, was used as photosensitizer in dye-sensitized solar cells (DSSCs). High power conversion efficiencies are reached not only with conventional I...

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Veröffentlicht in:ACS applied energy materials 2018-02, Vol.1 (2), p.751-756
Hauptverfasser: Dragonetti, Claudia, Magni, Mirko, Colombo, Alessia, Melchiorre, Fabio, Biagini, Paolo, Roberto, Dominique
Format: Artikel
Sprache:eng
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Zusammenfassung:A simple new heteroleptic copper dye, bearing one 2,9-dimesityl-1,10-phenanthroline and a 6,6′-dimethyl-2,2′-bipyridine-4,4′-dibenzoic acid anchoring ligand, was used as photosensitizer in dye-sensitized solar cells (DSSCs). High power conversion efficiencies are reached not only with conventional I–/I3 – electrolyte (40% relative conversion efficiency respect to N719) but, remarkably, also with a well-designed copper-based electrolyte. These proof-of-principle “full-copper” DSSCs open a fascinating route for environmentally friendly DSSCs.
ISSN:2574-0962
2574-0962
DOI:10.1021/acsaem.7b00196