Synthesis of Tetracyclic C 2‑Symmetric Ketiminium Salts and Evaluation as Catalysts for Epoxidation

Synthesis of Tetracyclic C 2‑Symmetric Ketiminium Salts and Evaluation as Catalysts for Epoxidation

Short synthetic routes to the nonplanar tetracyclic ketiminium salt A and two close analogs are described. These are helical nonplanar structures as shown by X-ray crystallography.

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Veröffentlicht in:Organic letters 2023-05, Vol.25 (19), p.3539-3542
Hauptverfasser: Reddy, G. Sudhakar, Corey, E. J.
Format: Artikel
Sprache:eng
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Zusammenfassung:Short synthetic routes to the nonplanar tetracyclic ketiminium salt A and two close analogs are described. These are helical nonplanar structures as shown by X-ray crystallography.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.3c01123