Unraveling the C 2 -Symmetric Azatetraquinane System. Simple, Enantioselective Syntheses

Unraveling the C 2 -Symmetric Azatetraquinane System. Simple, Enantioselective Syntheses

Concise stereocontrolled synthetic routes to the C -symmetric azatetraquinane (or, also, the enantiomer) are described. The successful execution of the synthesis involved innovation in the methodology for [3+2] cycloaddition and stereochemical control.

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Veröffentlicht in:Organic letters 2021-03, Vol.23 (6), p.2258-2262
Hauptverfasser: Reddy, G Sudhakar, Reddy, D Srinivas, Corey, E J
Format: Artikel
Sprache:eng
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Zusammenfassung:Concise stereocontrolled synthetic routes to the C -symmetric azatetraquinane (or, also, the enantiomer) are described. The successful execution of the synthesis involved innovation in the methodology for [3+2] cycloaddition and stereochemical control.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.1c00387