Molecular Defined Molybdenum–Pincer Complexes and Their Application in Catalytic Hydrogenations
A family of low-valent molybdenum complexes, supported by the pincer ligand ( i Pr2PCH2CH2)2NH, was prepared and characterized. After activation by NaBHEt3 coordination compounds 2 and 3-Cl were found to be suitable catalysts for the hydrogenation of ketones and olefins.
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| Veröffentlicht in: | Organometallics 2018-12, Vol.37 (23), p.4402-4408 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A family of low-valent molybdenum complexes, supported by the pincer ligand ( i Pr2PCH2CH2)2NH, was prepared and characterized. After activation by NaBHEt3 coordination compounds 2 and 3-Cl were found to be suitable catalysts for the hydrogenation of ketones and olefins. |
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| ISSN: | 0276-7333 1520-6041 |
| DOI: | 10.1021/acs.organomet.8b00410 |