Boraphosphaalkene Synthesis via Phosphaalkyne Insertion into 9‑Borafluorene

Boraphosphaalkene Synthesis via Phosphaalkyne Insertion into 9‑Borafluorene

The reaction of 1-adamantylphosphaalkyne with 9-phenyl-9-borafluorene resulted in the insertion of the PC unit into the endocyclic B–C bond, generating a seven-membered 1,3-boraphosphaalkene. The mechanism was investigated computationally, indicating that the reaction proceeds via a bond metathesis...

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Veröffentlicht in:Organometallics 2018-05, Vol.37 (10), p.1515-1518
Hauptverfasser: Yruegas, Sam, Barnard, Jonathan H, Al-Furaiji, Khalidah, Dutton, Jason L, Wilson, David J. D, Martin, Caleb D
Format: Artikel
Sprache:eng
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Zusammenfassung:The reaction of 1-adamantylphosphaalkyne with 9-phenyl-9-borafluorene resulted in the insertion of the PC unit into the endocyclic B–C bond, generating a seven-membered 1,3-boraphosphaalkene. The mechanism was investigated computationally, indicating that the reaction proceeds via a bond metathesis pathway.
ISSN:0276-7333
1520-6041
DOI:10.1021/acs.organomet.8b00248