Ferrocene-bis(phosphinimine) Nickel(II) and Palladium(II) Alkyl Complexes: Influence of the Fe–M (M = Ni and Pd) Interaction on Redox Activity and Olefin Coordination

The synthesis of several novel nickel­(II) and palladium­(II) ferrocene-bis­(phosphinimine) alkyl complexes containing iron–nickel and iron–palladium interactions is reported. The redox behavior of all complexes was evaluated electrochemically and chemically; in addition, reactions with weak nucleop...

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Veröffentlicht in:Organometallics 2017-11, Vol.36 (22), p.4394-4402
Hauptverfasser: Abubekerov, Mark, Khan, Saeed I, Diaconescu, Paula L
Format: Artikel
Sprache:eng
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Zusammenfassung:The synthesis of several novel nickel­(II) and palladium­(II) ferrocene-bis­(phosphinimine) alkyl complexes containing iron–nickel and iron–palladium interactions is reported. The redox behavior of all complexes was evaluated electrochemically and chemically; in addition, reactions with weak nucleophiles, such as acetonitrile and olefins, were also investigated. DFT calculations were performed to understand the electronic structure of the alkyl metal complexes.
ISSN:0276-7333
1520-6041
DOI:10.1021/acs.organomet.7b00626