Selective Formic Acid Dehydrogenation Catalyzed by Fe-PNP Pincer Complexes Based on the 2,6-Diaminopyridine Scaffold

Selective Formic Acid Dehydrogenation Catalyzed by Fe-PNP Pincer Complexes Based on the 2,6-Diaminopyridine Scaffold

Fe­(II) hydrido carbonyl complexes supported by PNP pincer ligands based on the 2,6-diaminopyridine scaffold were studied as homogeneous, non-precious-metal-based catalysts for selective formic acid dehydrogenation to hydrogen and carbon dioxide, reaching quantitative yields and high TONs under mild...

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Veröffentlicht in:Organometallics 2016-10, Vol.35 (19), p.3344-3349
Hauptverfasser: Mellone, Irene, Gorgas, Nikolaus, Bertini, Federica, Peruzzini, Maurizio, Kirchner, Karl, Gonsalvi, Luca
Format: Artikel
Sprache:eng
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Zusammenfassung:Fe­(II) hydrido carbonyl complexes supported by PNP pincer ligands based on the 2,6-diaminopyridine scaffold were studied as homogeneous, non-precious-metal-based catalysts for selective formic acid dehydrogenation to hydrogen and carbon dioxide, reaching quantitative yields and high TONs under mild reaction conditions.
ISSN:0276-7333
1520-6041
DOI:10.1021/acs.organomet.6b00551