Well-Defined Butadienyl Organocopper(I) Aggregates from Zirconacyclopentadienes and CuCl: Synthesis and Structural Characterization
Two examples of mixed alkenyl/aryl organocopper(I) aggregates possessing conjugated alkenyl/aryl C–Cu bonds were synthesized by transmetalation of zirconaindenes with CuCl. Single-crystal X-ray structural analysis revealed tetrameric and hexameric structures. Butadienyl copper(I) aggregates were a...
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| Veröffentlicht in: | Organometallics 2015-09, Vol.34 (17), p.4198-4201 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Two examples of mixed alkenyl/aryl organocopper(I) aggregates possessing conjugated alkenyl/aryl C–Cu bonds were synthesized by transmetalation of zirconaindenes with CuCl. Single-crystal X-ray structural analysis revealed tetrameric and hexameric structures. Butadienyl copper(I) aggregates were also synthesized and structurally characterized for further comparison. The preliminary reaction chemistry of the copper(I) aggregates was studied. |
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| ISSN: | 0276-7333 1520-6041 |
| DOI: | 10.1021/acs.organomet.5b00598 |