Visible-Light-Promoted Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by Rhodium(III) Porphyrins

Visible-Light-Promoted Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by Rhodium(III) Porphyrins

Visible-light-promoted hydrolysis of silanes catalyzed by (TAP)­Rh–I to produce silanols and dihydrogen efficiently under mild conditions was reported. (TAP)­Rh–H was observed as the key intermediate through stoichiometric activation of the Si–H bond by (TAP)­Rh–I. Addition of water drove the stoich...

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Veröffentlicht in:Organometallics 2015-12, Vol.34 (24), p.5754-5758
Hauptverfasser: Yu, Mengmeng, Jing, Huize, Liu, Xu, Fu, Xuefeng
Format: Artikel
Sprache:eng
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Zusammenfassung:Visible-light-promoted hydrolysis of silanes catalyzed by (TAP)­Rh–I to produce silanols and dihydrogen efficiently under mild conditions was reported. (TAP)­Rh–H was observed as the key intermediate through stoichiometric activation of the Si–H bond by (TAP)­Rh–I. Addition of water drove the stoichiometric activation of Si–H into catalysis.
ISSN:0276-7333
1520-6041
DOI:10.1021/acs.organomet.5b00521