Noncatalytic Liquid Phase Air Oxidation of Ethylbenzene to 1‑Phenyl Ethyl Hydroperoxide in Low Oxygen Volume Fraction
The catalyst- and solvent-free liquid phase air oxidation reaction of ethylbenzene (EB) to 1-phenyl ethyl hydroperoxide (PEHP) was investigated at scheduled temperature and pressure with a separate deacidifying zone. The oxidation reaction was done in the titanium fabricated reactor at an oxygen vol...
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Veröffentlicht in: | Organic process research & development 2018-02, Vol.22 (2), p.136-146 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The catalyst- and solvent-free liquid phase air oxidation reaction of ethylbenzene (EB) to 1-phenyl ethyl hydroperoxide (PEHP) was investigated at scheduled temperature and pressure with a separate deacidifying zone. The oxidation reaction was done in the titanium fabricated reactor at an oxygen volume fraction in the outlet gas less than 0.3%. The effects of several reaction parameters were studied in detail. In the optimal reaction conditions and instructions given in this work, the high selectivity to PEHP (above 95%) was achieved with EB conversion around 13%, and a clean feed (water and acid-free) was provided for the propene epoxidation reaction. |
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ISSN: | 1083-6160 1520-586X |
DOI: | 10.1021/acs.oprd.7b00284 |