Highly Efficient and Selective Hydrogenation of Sugars Catalyzed by Ru-MACHO-BH: Practical Synthesis of Sugar Alcohols

Highly Efficient and Selective Hydrogenation of Sugars Catalyzed by Ru-MACHO-BH: Practical Synthesis of Sugar Alcohols

A highly efficient synthesis of sugar alcohols was achieved by selective hydrogenation with a homogeneous catalyst. Ru-MACHO-BH, the PNHP-ruthenium catalyst, promoted the hydrogenation with extremely high reactivity and selectivity. The reaction could be applied to various kinds of mono- and disacch...

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Veröffentlicht in:Organic process research & development 2022-05, Vol.26 (5), p.1442-1449
Hauptverfasser: Ishikawa, Hiroki, Touge, Taichiro, Kuriyama, Wataru, Kida, Michio, Matsumura, Kazuhiko
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container_issue 5
container_start_page 1442
container_title Organic process research & development
container_volume 26
creator Ishikawa, Hiroki
Touge, Taichiro
Kuriyama, Wataru
Kida, Michio
Matsumura, Kazuhiko
description A highly efficient synthesis of sugar alcohols was achieved by selective hydrogenation with a homogeneous catalyst. Ru-MACHO-BH, the PNHP-ruthenium catalyst, promoted the hydrogenation with extremely high reactivity and selectivity. The reaction could be applied to various kinds of mono- and disaccharides and has been successfully run on a scale of several tens of grams.
doi_str_mv 10.1021/acs.oprd.2c00047
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title Highly Efficient and Selective Hydrogenation of Sugars Catalyzed by Ru-MACHO-BH: Practical Synthesis of Sugar Alcohols
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