Highly Efficient and Selective Hydrogenation of Sugars Catalyzed by Ru-MACHO-BH: Practical Synthesis of Sugar Alcohols
A highly efficient synthesis of sugar alcohols was achieved by selective hydrogenation with a homogeneous catalyst. Ru-MACHO-BH, the PNHP-ruthenium catalyst, promoted the hydrogenation with extremely high reactivity and selectivity. The reaction could be applied to various kinds of mono- and disacch...
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| Veröffentlicht in: | Organic process research & development 2022-05, Vol.26 (5), p.1442-1449 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A highly efficient synthesis of sugar alcohols was achieved by selective hydrogenation with a homogeneous catalyst. Ru-MACHO-BH, the PNHP-ruthenium catalyst, promoted the hydrogenation with extremely high reactivity and selectivity. The reaction could be applied to various kinds of mono- and disaccharides and has been successfully run on a scale of several tens of grams. |
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| ISSN: | 1083-6160 1520-586X |
| DOI: | 10.1021/acs.oprd.2c00047 |