Two-Dimensional Ultrathin Fe 3 Sn 2 Kagome Metal with Defect-Dependent Magnetic Property

Two-dimensional (2D) Fe Sn , which is a room-temperature ferromagnetic kagome metal, has potential applications in spintronic devices. However, the systematic synthesis and magnetic study of 2D Fe Sn single crystals have rarely been reported. Here we have synthesized 2D hexagonal and triangular Fe Sn nanosheets by controlling the amount of FeCl precursors in the chemical vapor deposition (CVD) method. It is found that the hexagonal Fe Sn nanosheets exist with Fe vacancy defects and show no obvious coercivity. While the triangular Fe Sn nanosheet has obvious hysteresis loops at room temperature, its coercivity first increases and then remains stable with an increase in temperature, which should result from the competition of the thermal activation mechanism and spin direction rotation mechanism. A first-principles calculation study shows that the Fe vacancy defects in Fe Sn can increase the distances between Fe atoms and weaken the ferromagnetism of Fe Sn . The resulting 2D Fe Sn nanosheets provide a new choice for spintronic devices.