Field-Cycling Relaxometry as a Molecular Rheology Technique: Common Analysis of NMR, Shear Modulus and Dielectric Loss Data of Polymers vs Dendrimers

Linear poly­(propylene glycol) (PPG) as well as a poly­(propyleneimine) (PPI) dendrimer with different molar masses (M) are investigated by field-cycling (FC) 1H NMR, shear rheology (G) and dielectric spectroscopy (DS). The results are compared in a reduced spectral density representation: the quantity R 1(ωτ α)/R 1 α(0), where R 1(ωτ α) is the master curve of the frequency dependent spin–lattice relaxation rate with τα denoting the local correlation time, is compared to the rescaled dynamic viscosity η′(ωτ α)/η′α(0). The quantities R 1 α(0) and η′α(0), respectively, are the zero-frequency limits of a simple liquid reference system. Analogously, the dielectric loss data can be included in the methodological comparison. This representation allows quantifying the sensitivity of each method with respect to the polymer-specific relaxation contribution. Introducing a “cumulative mode ratio” F i (M) for each technique i, which measures the zero-frequency plateau of the rescaled spectral density, characteristic power-law behavior F i (M) ∝ M α i is revealed. In the case of PPG, F NMR(M), F G(M), and F DS(M) essentially agree with predictions of the Rouse model yielding characteristic exponents α i . The crossover to entanglement dynamics is identified by a change in α i around M ≅ 10 kg/mol. The analysis is extended to the dendrimer which exhibits a relaxation behavior reminiscent of Rouse dynamics. Yet, clear evidence of entanglement is missing. The M-dependencies of the dendrimer diffusion coefficient D obtained by pulsed field-gradient NMR and the zero-shear viscosity are found to be D(M) ∝ M –1.6±0.2 and η­(M) ∝ M 1.9±0.2, respectively, in good agreement with our theoretical prediction η­(M) ∝ M 1/3 D –1(M). The close correspondence of R 1(ωτ α) with η′(ωτ α) establishes FC NMR as a powerful tool of “molecular rheology” accessing the microscopic processes underlying macroscopic rheological behavior of complex fluids.