Carbon-Coated Coaxial Cable-like ZnO@SiO 2 @C for High-Performance Lithium-Ion Battery Anode Materials

The practical applications of SiO anode material are limited by large volume changes and poor electronic conductivity. To reduce the effects of these problems, a carbon-coated coaxial cable-like ZnO@SiO @C composite material was prepared. ZnO has a certian electronic conductivity and an electrochemi...

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Veröffentlicht in:Langmuir 2024-12, Vol.40 (49), p.26239-26248
Hauptverfasser: Sun, Songyuan, Hu, Kaihan, Liu, Dongmei, Wu, Huigui, Zhu, Yuju, Chen, Jingbo
Format: Artikel
Sprache:eng
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Zusammenfassung:The practical applications of SiO anode material are limited by large volume changes and poor electronic conductivity. To reduce the effects of these problems, a carbon-coated coaxial cable-like ZnO@SiO @C composite material was prepared. ZnO has a certian electronic conductivity and an electrochemical activity, and the carbon layer can alleviate the volume variation of SiO , effectively improving the electronic conductivity and structural stability. At the same time, the carbon layer acts as a barrier to prevent direct contact between SiO and the electrolyte, thus promoting the formation of stable solid electrolyte interface films. Carbon-coated coaxial cable-like ZnO@SiO @C exhibits excellent electrochemical properties, with a discharge specific capacity of 480.3 mAh g after 500 cycles at a current density of 1 A g . The carbon-coated coaxial cable-like structure presents a potential application for alloying anode materials.
ISSN:0743-7463
1520-5827
DOI:10.1021/acs.langmuir.4c03751