Radical-Radical Reaction Dynamics Probed Using Millimeterwave Spectroscopy: Propargyl + NH 2 /ND 2

We apply chirped-pulse uniform flow millimeterwave (CPUF-mmW) spectroscopy to study the complex multichannel reaction dynamics in the reaction between the propargyl and amino radicals (C H + NH /ND ), a radical-radical reaction of importance in the gas-phase chemistry of astrochemical environments and combustion systems. The photolytically generated radicals are allowed to react in a well-characterized quasi-uniform supersonic flow, and mmW rotational spectroscopy (70-93 GHz) is used for simultaneous detection of the reaction products: HCN, HNC, HC N, DCN, DNC, and DC N, while spectral intensities of the measured pure-rotational lines allow product branching to be quantified. High-level electronic structure calculations were used for theoretical prediction of the reaction pathways and branching. Experimentally deduced product branching fractions were compared with the results from statistical simulations based on the RRKM theory. Product branching was found to be strongly dependent on the excess internal energy of the C H and NH /ND reactants.