Modeling of Liquid-Phase Oxidation of Para-xylene at a Low Oxygen Partial Pressure
The effect of a low oxygen partial pressure on the oxidation of the liquid phase of para-xylene (PX) was investigated in a continuous stirred tank reactor (CSTR). The kinetic model of the PX oxidation process was established with factors such as the reaction temperature, pressure, and catalyst. The...
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Veröffentlicht in: | Industrial & engineering chemistry research 2023-10, Vol.62 (40), p.16302-16308 |
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creator | Shang, Jianping Xue, Zhiqi Dong, Zhengliang Fu, Lin Qin, Xiaoping Peng, Tong Zheng, Jiapeng Fan, Hua-Jun Shawn |
description | The effect of a low oxygen partial pressure on the oxidation of the liquid phase of para-xylene (PX) was investigated in a continuous stirred tank reactor (CSTR). The kinetic model of the PX oxidation process was established with factors such as the reaction temperature, pressure, and catalyst. The reliability of this CSTR model of the reactor was validated through continuous PX oxidation experiments. The results showed that the reactor model fitted the experimental data well. This reactor model will provide not only insights into the industrial PX oxidation process but also support for the design and development of industrial reactors. |
doi_str_mv | 10.1021/acs.iecr.3c02552 |
format | Article |
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The kinetic model of the PX oxidation process was established with factors such as the reaction temperature, pressure, and catalyst. The reliability of this CSTR model of the reactor was validated through continuous PX oxidation experiments. The results showed that the reactor model fitted the experimental data well. This reactor model will provide not only insights into the industrial PX oxidation process but also support for the design and development of industrial reactors.</description><identifier>ISSN: 0888-5885</identifier><identifier>EISSN: 1520-5045</identifier><identifier>DOI: 10.1021/acs.iecr.3c02552</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>Kinetics, Catalysis, and Reaction Engineering</subject><ispartof>Industrial & engineering chemistry research, 2023-10, Vol.62 (40), p.16302-16308</ispartof><rights>2023 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-a233t-7c78bdebcc9e2149558d10e5a35fac8a4b409e1969f5c35823b32da5c261b6813</cites><orcidid>0000-0002-2078-7037 ; 0000-0002-6605-1877</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.iecr.3c02552$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.iecr.3c02552$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids></links><search><creatorcontrib>Shang, Jianping</creatorcontrib><creatorcontrib>Xue, Zhiqi</creatorcontrib><creatorcontrib>Dong, Zhengliang</creatorcontrib><creatorcontrib>Fu, Lin</creatorcontrib><creatorcontrib>Qin, Xiaoping</creatorcontrib><creatorcontrib>Peng, Tong</creatorcontrib><creatorcontrib>Zheng, Jiapeng</creatorcontrib><creatorcontrib>Fan, Hua-Jun Shawn</creatorcontrib><title>Modeling of Liquid-Phase Oxidation of Para-xylene at a Low Oxygen Partial Pressure</title><title>Industrial & engineering chemistry research</title><addtitle>Ind. Eng. Chem. Res</addtitle><description>The effect of a low oxygen partial pressure on the oxidation of the liquid phase of para-xylene (PX) was investigated in a continuous stirred tank reactor (CSTR). The kinetic model of the PX oxidation process was established with factors such as the reaction temperature, pressure, and catalyst. The reliability of this CSTR model of the reactor was validated through continuous PX oxidation experiments. The results showed that the reactor model fitted the experimental data well. This reactor model will provide not only insights into the industrial PX oxidation process but also support for the design and development of industrial reactors.</description><subject>Kinetics, Catalysis, and Reaction Engineering</subject><issn>0888-5885</issn><issn>1520-5045</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kMtOwzAQRS0EEqWwZ-kPwMWPTOssUQUUKagRgnU0cSbFVUjATkX79yRqt6xmce69Gh3GbpWcKanVPbo48-TCzDipAfQZmyjQUoBM4JxNpLVWgLVwya5i3EopAZJkwt5eu4oa3254V_PM_-x8JfJPjMTXe19h77t2JDkGFPtDQy1x7DnyrPsdEocNtSPrPTY8DxTjLtA1u6ixiXRzulP28fT4vlyJbP38snzIBGpjerFwC1tWVDqXklZJCmArJQnQQI3OYlImMiWVztManAGrTWl0heD0XJVzq8yUyeOuC12MgeriO_gvDIdCyWJ0UgxOitFJcXIyVO6OlZFsu11ohwf_j_8B-bVlWA</recordid><startdate>20231011</startdate><enddate>20231011</enddate><creator>Shang, Jianping</creator><creator>Xue, Zhiqi</creator><creator>Dong, Zhengliang</creator><creator>Fu, Lin</creator><creator>Qin, Xiaoping</creator><creator>Peng, Tong</creator><creator>Zheng, Jiapeng</creator><creator>Fan, Hua-Jun Shawn</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-2078-7037</orcidid><orcidid>https://orcid.org/0000-0002-6605-1877</orcidid></search><sort><creationdate>20231011</creationdate><title>Modeling of Liquid-Phase Oxidation of Para-xylene at a Low Oxygen Partial Pressure</title><author>Shang, Jianping ; Xue, Zhiqi ; Dong, Zhengliang ; Fu, Lin ; Qin, Xiaoping ; Peng, Tong ; Zheng, Jiapeng ; Fan, Hua-Jun Shawn</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a233t-7c78bdebcc9e2149558d10e5a35fac8a4b409e1969f5c35823b32da5c261b6813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Kinetics, Catalysis, and Reaction Engineering</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shang, Jianping</creatorcontrib><creatorcontrib>Xue, Zhiqi</creatorcontrib><creatorcontrib>Dong, Zhengliang</creatorcontrib><creatorcontrib>Fu, Lin</creatorcontrib><creatorcontrib>Qin, Xiaoping</creatorcontrib><creatorcontrib>Peng, Tong</creatorcontrib><creatorcontrib>Zheng, Jiapeng</creatorcontrib><creatorcontrib>Fan, Hua-Jun Shawn</creatorcontrib><collection>CrossRef</collection><jtitle>Industrial & engineering chemistry research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shang, Jianping</au><au>Xue, Zhiqi</au><au>Dong, Zhengliang</au><au>Fu, Lin</au><au>Qin, Xiaoping</au><au>Peng, Tong</au><au>Zheng, Jiapeng</au><au>Fan, Hua-Jun Shawn</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Modeling of Liquid-Phase Oxidation of Para-xylene at a Low Oxygen Partial Pressure</atitle><jtitle>Industrial & engineering chemistry research</jtitle><addtitle>Ind. Eng. Chem. Res</addtitle><date>2023-10-11</date><risdate>2023</risdate><volume>62</volume><issue>40</issue><spage>16302</spage><epage>16308</epage><pages>16302-16308</pages><issn>0888-5885</issn><eissn>1520-5045</eissn><abstract>The effect of a low oxygen partial pressure on the oxidation of the liquid phase of para-xylene (PX) was investigated in a continuous stirred tank reactor (CSTR). The kinetic model of the PX oxidation process was established with factors such as the reaction temperature, pressure, and catalyst. The reliability of this CSTR model of the reactor was validated through continuous PX oxidation experiments. The results showed that the reactor model fitted the experimental data well. This reactor model will provide not only insights into the industrial PX oxidation process but also support for the design and development of industrial reactors.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.iecr.3c02552</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-2078-7037</orcidid><orcidid>https://orcid.org/0000-0002-6605-1877</orcidid></addata></record> |
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title | Modeling of Liquid-Phase Oxidation of Para-xylene at a Low Oxygen Partial Pressure |
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