Solid-State Synthesis of Titanium-Doped Binary Strontium–Copper Oxide as a High-Performance Electrochemical Pseudocapacitive Electrode Nanomaterial

Ti-doped SrCu2O2 (TSCO) is prepared using a solid-state chemical reaction and applied as electrochemical pseudocapacitors. Different characterization techniques have been applied to confirm the crystallinity of the prepared TSCO, including an electrochemical test of the synthesized electrode materia...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Energy & fuels 2021-10, Vol.35 (20), p.16870-16881
Hauptverfasser: Barai, Hasi Rani, Barai, Paritosh, Roy, Madhusudan, Joo, Sang Woo
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 16881
container_issue 20
container_start_page 16870
container_title Energy & fuels
container_volume 35
creator Barai, Hasi Rani
Barai, Paritosh
Roy, Madhusudan
Joo, Sang Woo
description Ti-doped SrCu2O2 (TSCO) is prepared using a solid-state chemical reaction and applied as electrochemical pseudocapacitors. Different characterization techniques have been applied to confirm the crystallinity of the prepared TSCO, including an electrochemical test of the synthesized electrode material; TSCO demonstrates specific capacities (C s) of ca. 1167.6 and 661.8 F/g at a 5 mV s–1 scan rate and 0.02 A/g applied current density, respectively, which is greater than those of the undopped SCO. The increment of the specific capacity value can be explained by the insertion of Ti as doped material in the SCO, which simultaneously intensifies the rate of ion intercalation/deintercalation at the time of charging/discharging (CD). Even the cycling establishment for the TSCO is found to be excellent, and there is only a 4.4% decrease after 10 000 CD cycles. Therefore, TSCO will be highly useful to prepare an electrode able to achieve an immense performance for super capacitance energy storage applications.
doi_str_mv 10.1021/acs.energyfuels.1c01844
format Article
fullrecord <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_acs_energyfuels_1c01844</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>e68842044</sourcerecordid><originalsourceid>FETCH-LOGICAL-a301t-2e34a5cb1a999bdc0accaae280e3ff2d8e3351c73c3d06dbe8aa772455d915653</originalsourceid><addsrcrecordid>eNqFkE1OwzAQRi0EEqVwBnyBFDuO87OEUihSBZVS1tHUnrSukjiyU0R33AFxQU5CqlaIHauRZr43mnmEXHM24izkN6D8CBt0q125xcqPuGI8jaITMuAyZIFkYXZKBixNk4DFYXROLrzfMMZikcoB-cptZXSQd9AhzXdNt0ZvPLUlXZgOGrOtg3vboqZ3pgG3o3nnbNP17e-Pz7FtW3T05d1opOAp0KlZrYM5utK6GhqFdFKh6gm1xtooqOjc41ZbBS0o05m330C_4BkaW_dXOAPVJTkrofJ4daxD8vowWYynwezl8Wl8OwtAMN4FIYoIpFpyyLJsqRUDpQAwTBmKsgx1ikJIrhKhhGaxXmIKkCRhJKXOuIylGJLksFc5673Dsmidqfs_C86Kvd2it1v8sVsc7fakOJD7wMZuXQP76T_UD7gSils</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Solid-State Synthesis of Titanium-Doped Binary Strontium–Copper Oxide as a High-Performance Electrochemical Pseudocapacitive Electrode Nanomaterial</title><source>ACS Publications</source><creator>Barai, Hasi Rani ; Barai, Paritosh ; Roy, Madhusudan ; Joo, Sang Woo</creator><creatorcontrib>Barai, Hasi Rani ; Barai, Paritosh ; Roy, Madhusudan ; Joo, Sang Woo</creatorcontrib><description>Ti-doped SrCu2O2 (TSCO) is prepared using a solid-state chemical reaction and applied as electrochemical pseudocapacitors. Different characterization techniques have been applied to confirm the crystallinity of the prepared TSCO, including an electrochemical test of the synthesized electrode material; TSCO demonstrates specific capacities (C s) of ca. 1167.6 and 661.8 F/g at a 5 mV s–1 scan rate and 0.02 A/g applied current density, respectively, which is greater than those of the undopped SCO. The increment of the specific capacity value can be explained by the insertion of Ti as doped material in the SCO, which simultaneously intensifies the rate of ion intercalation/deintercalation at the time of charging/discharging (CD). Even the cycling establishment for the TSCO is found to be excellent, and there is only a 4.4% decrease after 10 000 CD cycles. Therefore, TSCO will be highly useful to prepare an electrode able to achieve an immense performance for super capacitance energy storage applications.</description><identifier>ISSN: 0887-0624</identifier><identifier>EISSN: 1520-5029</identifier><identifier>DOI: 10.1021/acs.energyfuels.1c01844</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>Batteries and Energy Storage</subject><ispartof>Energy &amp; fuels, 2021-10, Vol.35 (20), p.16870-16881</ispartof><rights>2021 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a301t-2e34a5cb1a999bdc0accaae280e3ff2d8e3351c73c3d06dbe8aa772455d915653</citedby><cites>FETCH-LOGICAL-a301t-2e34a5cb1a999bdc0accaae280e3ff2d8e3351c73c3d06dbe8aa772455d915653</cites><orcidid>0000-0001-5915-8425 ; 0000-0001-9102-4224</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.energyfuels.1c01844$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.energyfuels.1c01844$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2763,27075,27923,27924,56737,56787</link.rule.ids></links><search><creatorcontrib>Barai, Hasi Rani</creatorcontrib><creatorcontrib>Barai, Paritosh</creatorcontrib><creatorcontrib>Roy, Madhusudan</creatorcontrib><creatorcontrib>Joo, Sang Woo</creatorcontrib><title>Solid-State Synthesis of Titanium-Doped Binary Strontium–Copper Oxide as a High-Performance Electrochemical Pseudocapacitive Electrode Nanomaterial</title><title>Energy &amp; fuels</title><addtitle>Energy Fuels</addtitle><description>Ti-doped SrCu2O2 (TSCO) is prepared using a solid-state chemical reaction and applied as electrochemical pseudocapacitors. Different characterization techniques have been applied to confirm the crystallinity of the prepared TSCO, including an electrochemical test of the synthesized electrode material; TSCO demonstrates specific capacities (C s) of ca. 1167.6 and 661.8 F/g at a 5 mV s–1 scan rate and 0.02 A/g applied current density, respectively, which is greater than those of the undopped SCO. The increment of the specific capacity value can be explained by the insertion of Ti as doped material in the SCO, which simultaneously intensifies the rate of ion intercalation/deintercalation at the time of charging/discharging (CD). Even the cycling establishment for the TSCO is found to be excellent, and there is only a 4.4% decrease after 10 000 CD cycles. Therefore, TSCO will be highly useful to prepare an electrode able to achieve an immense performance for super capacitance energy storage applications.</description><subject>Batteries and Energy Storage</subject><issn>0887-0624</issn><issn>1520-5029</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFkE1OwzAQRi0EEqVwBnyBFDuO87OEUihSBZVS1tHUnrSukjiyU0R33AFxQU5CqlaIHauRZr43mnmEXHM24izkN6D8CBt0q125xcqPuGI8jaITMuAyZIFkYXZKBixNk4DFYXROLrzfMMZikcoB-cptZXSQd9AhzXdNt0ZvPLUlXZgOGrOtg3vboqZ3pgG3o3nnbNP17e-Pz7FtW3T05d1opOAp0KlZrYM5utK6GhqFdFKh6gm1xtooqOjc41ZbBS0o05m330C_4BkaW_dXOAPVJTkrofJ4daxD8vowWYynwezl8Wl8OwtAMN4FIYoIpFpyyLJsqRUDpQAwTBmKsgx1ikJIrhKhhGaxXmIKkCRhJKXOuIylGJLksFc5673Dsmidqfs_C86Kvd2it1v8sVsc7fakOJD7wMZuXQP76T_UD7gSils</recordid><startdate>20211021</startdate><enddate>20211021</enddate><creator>Barai, Hasi Rani</creator><creator>Barai, Paritosh</creator><creator>Roy, Madhusudan</creator><creator>Joo, Sang Woo</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-5915-8425</orcidid><orcidid>https://orcid.org/0000-0001-9102-4224</orcidid></search><sort><creationdate>20211021</creationdate><title>Solid-State Synthesis of Titanium-Doped Binary Strontium–Copper Oxide as a High-Performance Electrochemical Pseudocapacitive Electrode Nanomaterial</title><author>Barai, Hasi Rani ; Barai, Paritosh ; Roy, Madhusudan ; Joo, Sang Woo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a301t-2e34a5cb1a999bdc0accaae280e3ff2d8e3351c73c3d06dbe8aa772455d915653</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Batteries and Energy Storage</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Barai, Hasi Rani</creatorcontrib><creatorcontrib>Barai, Paritosh</creatorcontrib><creatorcontrib>Roy, Madhusudan</creatorcontrib><creatorcontrib>Joo, Sang Woo</creatorcontrib><collection>CrossRef</collection><jtitle>Energy &amp; fuels</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Barai, Hasi Rani</au><au>Barai, Paritosh</au><au>Roy, Madhusudan</au><au>Joo, Sang Woo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solid-State Synthesis of Titanium-Doped Binary Strontium–Copper Oxide as a High-Performance Electrochemical Pseudocapacitive Electrode Nanomaterial</atitle><jtitle>Energy &amp; fuels</jtitle><addtitle>Energy Fuels</addtitle><date>2021-10-21</date><risdate>2021</risdate><volume>35</volume><issue>20</issue><spage>16870</spage><epage>16881</epage><pages>16870-16881</pages><issn>0887-0624</issn><eissn>1520-5029</eissn><abstract>Ti-doped SrCu2O2 (TSCO) is prepared using a solid-state chemical reaction and applied as electrochemical pseudocapacitors. Different characterization techniques have been applied to confirm the crystallinity of the prepared TSCO, including an electrochemical test of the synthesized electrode material; TSCO demonstrates specific capacities (C s) of ca. 1167.6 and 661.8 F/g at a 5 mV s–1 scan rate and 0.02 A/g applied current density, respectively, which is greater than those of the undopped SCO. The increment of the specific capacity value can be explained by the insertion of Ti as doped material in the SCO, which simultaneously intensifies the rate of ion intercalation/deintercalation at the time of charging/discharging (CD). Even the cycling establishment for the TSCO is found to be excellent, and there is only a 4.4% decrease after 10 000 CD cycles. Therefore, TSCO will be highly useful to prepare an electrode able to achieve an immense performance for super capacitance energy storage applications.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.energyfuels.1c01844</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0001-5915-8425</orcidid><orcidid>https://orcid.org/0000-0001-9102-4224</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0887-0624
ispartof Energy & fuels, 2021-10, Vol.35 (20), p.16870-16881
issn 0887-0624
1520-5029
language eng
recordid cdi_crossref_primary_10_1021_acs_energyfuels_1c01844
source ACS Publications
subjects Batteries and Energy Storage
title Solid-State Synthesis of Titanium-Doped Binary Strontium–Copper Oxide as a High-Performance Electrochemical Pseudocapacitive Electrode Nanomaterial
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-11T05%3A01%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Solid-State%20Synthesis%20of%20Titanium-Doped%20Binary%20Strontium%E2%80%93Copper%20Oxide%20as%20a%20High-Performance%20Electrochemical%20Pseudocapacitive%20Electrode%20Nanomaterial&rft.jtitle=Energy%20&%20fuels&rft.au=Barai,%20Hasi%20Rani&rft.date=2021-10-21&rft.volume=35&rft.issue=20&rft.spage=16870&rft.epage=16881&rft.pages=16870-16881&rft.issn=0887-0624&rft.eissn=1520-5029&rft_id=info:doi/10.1021/acs.energyfuels.1c01844&rft_dat=%3Cacs_cross%3Ee68842044%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true