A Robust Metal-Metalloporphyrin Framework Based upon a Secondary Building Unit of Infinite Nickel Oxide Chain

A Robust Metal-Metalloporphyrin Framework Based upon a Secondary Building Unit of Infinite Nickel Oxide Chain

Herein we report the construction of a robust metal-metalloporphyrin framework that is based upon a rare secondary building unit of infinite nickel oxide chain. The constructed MMPF-20 exhibits permanent porosity and selective adsorption of CO2 over CH4 as well as demonstrates interesting catalytic...

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Veröffentlicht in:Crystal growth & design 2016-02, Vol.16 (2), p.1005-1009
Hauptverfasser: Zhang, Weijie, Gao, Wenyang, Pham, Tony, Jiang, Pingping, Ma, Shengqian
Format: Artikel
Sprache:eng
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Zusammenfassung:Herein we report the construction of a robust metal-metalloporphyrin framework that is based upon a rare secondary building unit of infinite nickel oxide chain. The constructed MMPF-20 exhibits permanent porosity and selective adsorption of CO2 over CH4 as well as demonstrates interesting catalytic performances in the context of olefin epoxidation.
ISSN:1528-7483
1528-7505
DOI:10.1021/acs.cgd.5b01548