The dehydrative etherification of benzyl alcohols via mechanochemical reaction

The dehydrative etherification of benzyl alcohols via mechanochemical reaction

[Display omitted] A facile, solvent-free, lower-cost, and efficient high-speed ball milling reaction catalyzed by Cu(NO3)2·3H2O/P2O5 is developed for the synthesis of symmetric ethers from dehydration of benzyl alcohols by taking a benzylic carbocation as intermediate.

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Veröffentlicht in:Tetrahedron letters 2022-06, Vol.99, p.153838, Article 153838
Hauptverfasser: Bian, Meng-Hua, Lu, Li-Yu, Zhang, Pu, Guo, Zhi-Xin
Format: Artikel
Sprache:eng
Schlagworte:
Cu(NO3)2·3H2O
Dehydration
Ether
Mechanochemistry
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Zusammenfassung:[Display omitted] A facile, solvent-free, lower-cost, and efficient high-speed ball milling reaction catalyzed by Cu(NO3)2·3H2O/P2O5 is developed for the synthesis of symmetric ethers from dehydration of benzyl alcohols by taking a benzylic carbocation as intermediate.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2022.153838