The [1,2]- and [1,4]-Wittig rearrangement

The [1,2]- and [1,4]-Wittig rearrangement

This review traces the development of the [1,2]- and [1,4]-Wittig rearrangement and their applications in organic synthesis for the past twenty years. The mechanisms are discussed along with detailed analysis of reaction scope and stereochemistry. Applications are reviewed in the context of synthesi...

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Veröffentlicht in:Tetrahedron 2020-01, Vol.76 (5), p.130857, Article 130857
Hauptverfasser: Wang, Fan, Wang, Juhui, Zhang, Yan, Yang, Jingyue
Format: Artikel
Sprache:eng
Schlagworte:
[1,2]-Wittig rearrangement
[1,4]-Wittig rearrangement
Application
Mechanism
Scope
Stereochemistry
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Beschreibung
Zusammenfassung:This review traces the development of the [1,2]- and [1,4]-Wittig rearrangement and their applications in organic synthesis for the past twenty years. The mechanisms are discussed along with detailed analysis of reaction scope and stereochemistry. Applications are reviewed in the context of synthesis of chiral ligands, ring constriction reactions and tandem reactions with the [1,2]-/[1,4]-Wittig rearrangements involved, etc. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2019.130857