Mechanisms of surface nanostructuring of Al2O3 and MgO by grazing incidence irradiation with swift heavy ions

•Ion tracks have been produced on the surfaces of Al2O3 and MgO.•Differences in track morphologies were attributed to the properties of the melt.•MD simulations revealed absence of ion tracks in the bulk is due to recrystallisation. We experimentally discovered that Al2O3 and MgO exhibit well-pronou...

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Veröffentlicht in:Surfaces and interfaces 2021-12, Vol.27, p.101508, Article 101508
Hauptverfasser: Karlušić, M., Rymzhanov, R.A., O'Connell, J.H., Bröckers, L., Luketić, K. Tomić, Siketić, Z., Fazinić, S., Dubček, P., Jakšić, M., Provatas, G., Medvedev, N., Volkov, A.E., Schleberger, M.
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Sprache:eng
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Zusammenfassung:•Ion tracks have been produced on the surfaces of Al2O3 and MgO.•Differences in track morphologies were attributed to the properties of the melt.•MD simulations revealed absence of ion tracks in the bulk is due to recrystallisation. We experimentally discovered that Al2O3 and MgO exhibit well-pronounced nanometric modifications on the surfaces when irradiated under grazing incidence with 23 MeV I beam, in contrast to normal incidence irradiation with the same ion beam when no damage was found. Moreover, ions in these two materials produce notably different structures: grooves surrounded with nanohillocks on MgO surfaces vs. smoother, roll-like discontinuous structures on the surfaces of Al2O3. To explain these results, detailed numerical simulations were performed. We identified that a presence of the surface inhibits recrystallization process, thereby preventing transient tracks from recovery, and thus forming observable nanopatterns. Furthermore, a difference in the viscosities in molten states in Al2O3 vs. MgO explains the differences in the created nanostructures. Our results thus provide a deeper understanding of the fundamental processes of surface nanostructuring, potentially allowing for controlled production of periodic surface nanopatterns. [Display omitted]
ISSN:2468-0230
2468-0230
DOI:10.1016/j.surfin.2021.101508